A new free recoverable and reusable mono-alkaloid-type ligand and its use in preparation of ethyl (2R,3S)-2,3-dihydroxy-3-phenylpropionate

被引：2

作者：

Wang, Qiao Feng ^{[1
]}

Chen, Hui ^{[1
]}

Zhao, Yan ^{[1
]}

Li, Xiao Ye ^{[1
]}

Zhang, Sheng Yong ^{[1
]}

机构：

[1] Fourth Mil Med Univ, Res Ctr Chirotechnol, Xian 710032, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2009年 / 20卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Cinchona alkaloid; Recoverable and reusable ligand; Ethyl (2R,3S)-2,3-dihydroxy-3-phenylpropionate; CATALYTIC ASYMMETRIC DIHYDROXYLATION; POLYMER-BOUND LIGAND; OPEG-OME; OLEFINS; EFFICIENT;

D O I：

10.1016/j.cclet.2009.02.018

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new free recoverable and reusable mono-alkaloid-type ligand has been synthesized by a simple method. With highly polar groups, the ligand can be recycled and reused eight times to prepare ethyl (2R,3S)-2,3-dihydroxy-3-phenylpropionate with high yield and ee via asymmetric dihydroxylation (AD) reaction. (C) 2009 Sheng Yong Zhang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

引用

页码：763 / 766

页数：4

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