2-Hydroxylation of 1,3-Diketones with Atmospheric Oxygen

被引：17

作者：

Li, Zheng ^{[1
]}

Li, Tianpeng ^{[1
]}

Li, Jiasheng ^{[1
]}

He, Lili ^{[1
]}

Jia, Xianggui ^{[1
]}

Yang, Jingya ^{[1
]}

机构：

[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China

来源：

SYNLETT | 2015年 / 26卷 / 20期

基金：

中国国家自然科学基金;

关键词：

diketones; hydroxylations; oxidations; green chemistry; BETA-DICARBONYL COMPOUNDS; CATALYZED ALPHA-HYDROXYLATION; 1,3-DICARBONYL COMPOUNDS; STEREOCONTROL; OXIDATION;

D O I：

10.1055/s-0035-1560647

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient method for the 2-hydroxylation of 1,3-diketones by using atmospheric oxygen as an oxidant under transition-metal-free condition is described. The protocol has the advantages of using an inexpensive and stable oxidant, producing high yields, and requiring ecofriendly conditions.

引用

页码：2863 / 2865

页数：3

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