Measurement of SO2 solubility in ionic liquids

被引:309
作者
Anderson, Jessica L. [1 ]
Dixon, JaNeille K. [1 ]
Maginn, Edward J. [1 ]
Brennecke, Joan F. [1 ]
机构
[1] Univ Notre Dame, Dept Chem & Biomol Engn, Notre Dame, IN 46556 USA
关键词
D O I
10.1021/jp063547u
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Measurements of the solubility of sulfur dioxide (SO2) in the ionic liquids 1-n-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([hmim][Tf2N]) and 1-n-hexyl-3-methylpyridinium bis(trifluoromethylsulfonyl) imide ([hmpy][Tf2N]) at temperatures from 25 to 60 degrees C and pressures up to 4 bar indicate that large amounts (up to 85 mol %) of SO2 dissolve in ionic liquids by simple physical absorption.
引用
收藏
页码:15059 / 15062
页数:4
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