Use of nitrogen as a blowing agent for the production of fine-celled high-density polyethylene foams

被引:44
作者
Lee, John W. S. [1 ]
Park, Chul B. [1 ]
机构
[1] Univ Toronto, Dept Mech & Ind Engn, Microcellular Plast Mfg Lab, Toronto, ON M5S 3G8, Canada
关键词
blowing agents; foam extrusion; nitrogen; polyethylene (PE);
D O I
10.1002/mame.200600203
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
While many experiments have been performed to examine the effects of administering CO2 as a blowing agent in the foaming process, very few studies have investigated the use of N-2 for this purpose. In this study, foaming experiments were conducted in extrusion using HDPE as a polymeric material and N-2 as a blowing agent. Talc was used as a nucleating agent, and three different pressure-drop rates were applied to study the effects of pressure-drop rates on HDPE foams. The experimental results revealed that the void fraction of high-density foams blown with N-2 was not affected by the die temperature, contrasting the situation in low-density foams. Surprisingly, it was the cell density which determined the void fraction of high-density foams. It was also found that the use of talc significantly increased the cell density and the void fraction of the foams and minimized the role played by the pressure-drop rate in cell nucleation.
引用
收藏
页码:1233 / 1244
页数:12
相关论文
共 17 条
[1]  
Behravesh AH, 1998, CELL POLYM, V17, P309
[2]  
BEHRAVESH AH, 1996, POLYM PREPRINTS, V37, P767
[3]   THE NUCLEATION OF MICROCELLULAR THERMOPLASTIC FOAM WITH ADDITIVES .1. THEORETICAL CONSIDERATIONS [J].
COLTON, JS ;
SUH, NP .
POLYMER ENGINEERING AND SCIENCE, 1987, 27 (07) :485-492
[4]   THE NUCLEATION OF MICROCELLULAR THERMOPLASTIC FOAM WITH ADDITIVES .2. EXPERIMENTAL RESULTS AND DISCUSSION [J].
COLTON, JS ;
SUH, NP .
POLYMER ENGINEERING AND SCIENCE, 1987, 27 (07) :493-499
[5]   Structure optimization of polycaprolactone foams by using mixtures of CO2 and N2 as blowing agents [J].
Di Maio, E ;
Mensitieri, G ;
Iannace, S ;
Nicolais, L ;
Li, W ;
Flumerfelt, RW .
POLYMER ENGINEERING AND SCIENCE, 2005, 45 (03) :432-441
[6]   Micropreemption synthesis: An enabling mechanism for multitask VLSI systems [J].
Kim, K ;
Karri, R ;
Potkonjak, M .
IEEE TRANSACTIONS ON COMPUTER-AIDED DESIGN OF INTEGRATED CIRCUITS AND SYSTEMS, 2006, 25 (01) :19-30
[7]   Challenge to extrusion of low-density microcellular polycarbonate foams using supercritical carbon dioxide [J].
Lee, JWS ;
Wang, KY ;
Park, CB .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (01) :92-99
[8]   Fundamental foaming mechanisms governing the volume expansion of extruded polypropylene foams [J].
Naguib, HE ;
Park, CB ;
Reichelt, N .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 91 (04) :2661-2668
[9]   Strategies for achieving ultra low-density polypropylene foams [J].
Naguib, HE ;
Park, CB .
POLYMER ENGINEERING AND SCIENCE, 2002, 42 (07) :1481-1492
[10]   EFFECT OF THE PRESSURE DRIP RATE ON CELL NUCLEATION IN CONTINUOUS PROCESSING OF MICROCELLULAR POLYMERS [J].
PARK, CB ;
BALDWIN, DF ;
SUH, NP .
POLYMER ENGINEERING AND SCIENCE, 1995, 35 (05) :432-440