Syngas production by partial oxidation of methane: dependence of reactivity on catalyst properties and contact time

被引：0

作者：

Basini, L ^{[1
]}

DAmore, M ^{[1
]}

Fornasari, G ^{[1
]}

Matteuzzi, D ^{[1
]}

Sanfilippo, D ^{[1
]}

Trifiro, F ^{[1
]}

Vaccari, A ^{[1
]}

机构：

[1] DEPT IND CHEM & MAT, I-40136 BOLOGNA, ITALY

来源：

NATURAL GAS CONVERSION IV | 1997年 / 107卷

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of very short contact times on molecular aspects of the reaction mechanism for the partial oxidation of methane with a rhodium catalyst was studied using a fixed bed micro-reactor and a reaction chamber equipped for DRIFT and mass spectrometry. Small surface rhodium carbonyl clusters were selectively generated at contact times > 10(-2), while at shorter contact times these species were not present. Correspondingly different catalytic activities and selectivities were observed.

引用

页码：429 / 434

页数：6

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