Screening of an ionic liquid as medium for photochemical reactions

被引：76

作者：

Alvaro, M ^{[1
]}

Ferrer, B ^{[1
]}

García, H ^{[1
]}

Narayana, M ^{[1
]}

机构：

[1] Univ Politecn Valencia, Dept Quim, Inst Tecnol Quim, CSIC, Valencia 46022, Spain

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 362卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(02)01138-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (bmim-PF6) has been used as solvent for a series of representative photochemical reactions covering energy transfer, hydrogen transfer and electron transfer. Low oxygen solubility, slow molecular diffusion, enhancement of the triplet excited state and radical ion lifetimes and weakening of the CT interactions are the major characteristics featured for this ionic melt. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：435 / 440

页数：6

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