Viscoelastic properties of poly(2-vinylpyridine) in bulk and solution

被引：31
|
作者：
Takahashi, Y
Ochiai, N
Matsushita, Y
Noda, I
机构：
[1] Department of Applied Chemistry, Nagoya University, Chikusa-ku
[2] Dai-ichi Kogyo Seiyaku Co., Ltd., Shimogyo-ku, Kyoto 600, 55, Nishi-shichijo, Higashikubocho
[3] Neutron Scattering Laboratory, ISSP, University of Tokyo, Tokai, Ibaraki 319-11
来源：
POLYMER JOURNAL | 1996年 / 28卷 / 12期
关键词：
poly(2-vinylpyridine); zero-shear viscosity; plateau modulus; steady state compliance;
D O I：
10.1295/polymj.28.1065
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Viscoelastic properties of poly(2-vinylpyridine) (P2VP) over a wide range of molecular weight (M) were studied in bulk and solution. It was found that the absolute values of zero-shear viscosity eta(0) of P2VP in bulk and in alpha-chloronaphtharene (alpha CN) are practically the same as those of polystyrene (PS) over whole experimental range of M. The temperature dependence of eta(0) in bulk is also the same. It is concluded that among Various polymers so far studied, P2VP and PS have very similar viscoelastic properties in both bulk and a good solvent (alpha CN), though the plateau modulus G(N)(0) and steady state compliance J(e) of P2VP are slightly different from those of PS.
引用
收藏
页码：1065 / 1070
页数：6
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