Volumetric and dielectric characterization and analysis of internal structure of binary mixtures of 2-ethoxyethanol with ethylene glycol, diethylene glycol, triethylene glycol, and tetraethylene glycol at T=(293.15, 298.15 and 303.15) K

被引：24

作者：

Kinart, Cezary M. ^{[1
]}

Klimczak, Magdalena ^{[1
]}

Kinart, Wojciech J. ^{[2
]}

机构：

[1] Univ Lodz, Dept Phys Chem, PL-90236 Lodz, Poland

[2] Univ Lodz, Dept Organ Chem, PL-90136 Lodz, Poland

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2009年 / 145卷 / 01期

关键词：

2-Ethoxyethanol; Ethylene glycol; Diethylene glycol; Triethylene glycol; Tetraethylene glycol; Density; Relative permittivity; EXCESS MOLAR VOLUMES; SOLVENT SYSTEM; ISENTROPIC COMPRESSIBILITIES; RELATIVE PERMITTIVITIES; DIFFERENT TEMPERATURES; REFRACTIVE-INDEX; DENSITIES; SOUND; CONSTANTS; SPEEDS;

D O I：

10.1016/j.molliq.2008.11.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Densities and relative permittivities, at T=(293.15,298.15 and 303.15) K, in the binary mixtures of 2-ethoxyethanol with ethylene glycol, diethylene glycol, triethylene glycol and tetraethylene glycol have been measured as a function of composition. From the experimental data the excess molar volumes and deviations in the relative permittivity have been calculated. The results are discussed in terms of intermolecular interactions and structural properties of studied binary mixtures. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：8 / 13

页数：6

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[2]

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