All-Metal Mesoporous Nanocolloids: Solution-Phase Synthesis of Core-Shell Pd@Pt Nanoparticles with a Designed Concave Surface

被引:208
作者
Ataee-Esfahani, Hamed [1 ]
Imura, Masataka [1 ]
Yamauchi, Yusuke [1 ,2 ]
机构
[1] Natl Inst Mat Sci, World Premier Int WPI Res Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan
[2] Waseda Univ, Fac Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan
关键词
colloids; mesoporous materials; nanoparticles; surfactants; template synthesis; IRON-GROUP METALS; ONE-POT SYNTHESIS; CARBON NANOPARTICLES; PLATINUM NANOCRYSTALS; BIMETALLIC NANODENDRITES; ANOMALOUS CODEPOSITION; FACILE SYNTHESIS; SHAPE CONTROL; SILICA; NANOSTRUCTURES;
D O I
10.1002/anie.201307126
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Colloidal Pd@Pt nanoparticles with uniform mesopores can be synthesized in one step by a facile solution-phase method involving slow reduction of metal species in strong acidic media. In this system, F127 micelles can directly act as a template to form the mesopores in the product, and the greater reducibility of the Pd species leads to the desired core-shell Pd@Pt nanocolloids. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:13611 / 13615
页数:5
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