In situ hydrothermal synthesis and structural characterization of two novel CdII-tetrazole coordination polymers

被引:5
作者
Xiao, Jie [1 ]
Wang, Wen-Xiang [1 ]
Lin, Jin-Rui [1 ]
Zhao, Hong [1 ]
机构
[1] Southeast Univ, Sch Chem & Chem Engn, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China
基金
中国国家自然科学基金;
关键词
Cadmium; Tetrazole; Metal-organic frameworks; Hydrothermal synthesis; AZIDE;
D O I
10.1016/j.molstruc.2009.06.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The in situ hydrothermal reactions of 4-nitrobenzonitrile with Cd(ClO4)(2) and CdCl2 afforded two novel Cd-II-tetrazole coordination polymers, 2D network {[Cd(H2O)(2)(4-nptz)(2)](H2O)(2)}(n) (1) and 1D double chains [Cd(H2O)2(4-nptz)(2)](n) (2). Their synthesis, solid-state structure, and XRPD patterns are reported. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:98 / 103
页数:6
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