Threaded structures based on the recognition of 1, 5-dinaphtho-crown ethers to paraquat and vinylogous viologen derivatives: host-guest complexations, X-ray crystal structures, and self-assembly superstructures

被引:1
|
作者
Zhou, Qizhong [1 ,2 ]
Su, Liangjun [1 ]
Gu, Haining [3 ]
Jiang, Tiansheng [4 ]
Qiu, Fangli [1 ]
Ye, Yuyuan [1 ]
Jiang, Huajiang [1 ]
Han, Deman [1 ]
Dai, Guoliang [1 ]
Ren, Shibin [1 ]
Chen, Rener [1 ]
机构
[1] Taizhou Univ, Dept Chem, Taizhou 318000, Peoples R China
[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[3] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
[4] Univ Houston, Coll Nat Sci & Math, Houston, TX 77204 USA
基金
中国博士后科学基金;
关键词
Crown ether; Pseudorotaxane; Self-assembly; Host-guest system; Supramolecular chemistry; HYDROGEN-BONDING INTERACTIONS; SUPRAMOLECULAR POLYMERS; PSEUDOCRYPTAND-TYPE; MOLECULAR MACHINES; DONOR-ACCEPTOR; RING; CRYPTAND/PARAQUAT; SELECTIVITY; CRYPTANDS; NETWORK;
D O I
10.1016/j.tetlet.2014.03.033
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Host-guest complexation between two 1,5-dinaphtho-crown ethers and two paraquat derivatives has been studied. By self-assembly of 1,5-dinaphtho-44-crown-12 (DNP44C12) 1 with vinylogous viologen 4, a linear [2]pseudorotaxane array forms in the solid state by PF6- anion linkages. Moreover, the complexation between 1,5-dinaphtho-50-crown-14 (DNP50C14) 2 and paraquat 3 also leads to the formation of a linear [2]pseudorotaxane superstructure in the solid state driven by pi-pi stacking. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2541 / 2544
页数:4
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