Facile sonochemical synthesis of perovskite-type SrTiO3 nanocubes with reduced graphene oxide nanocatalyst for an enhanced electrochemical detection of α-amino acid (tryptophan)

被引:89
作者
Govindasamy, Mani [1 ]
Wang, Sea-Fue [1 ]
Pan, Wei Chih [1 ]
Subramanian, Bowya [2 ,3 ]
Ramalingam, R. Jothi [4 ]
Al-lohedan, Hamad [4 ]
机构
[1] Natl Taipei Univ Technol, Dept Mat & Mineral Resources Engn, 1,Sec 3,Chung Hsiao East Rd, Taipei 106, Taiwan
[2] Natl Taipei Univ Technol, Dept Elect Engn & Comp Sci, 1,Sec 3,Chung Hsiao East Rd, Taipei 106, Taiwan
[3] KSR Coll Engn, Dept Informat Technol, Tiruchengode, Tamil Nadu, India
[4] King Saud Univ, Coll Sci, Chem Dept, Surfactant Res Chair, POB 2455, Riyadh 11451, Saudi Arabia
关键词
Sonochemical synthesis; Perovskite-type SrTiO3; Reduced graphene oxide; Electrochemical sensor; Amino acid detection; CARBON-PASTE ELECTRODE; HIGHLY SENSITIVE DETERMINATION; MICROWAVE-ASSISTED SYNTHESIS; OXIDATIVE STRESS BIOMARKER; CORE-SHELL NANOCOMPOSITE; BORON-DOPED DIAMOND; VOLTAMMETRIC DETERMINATION; METHYL PARATHION; SELECTIVE DETERMINATION; NANOPARTICLES;
D O I
10.1016/j.ultsonch.2019.04.004
中图分类号
O42 [声学];
学科分类号
070206 ; 082403 ;
摘要
In this paper, perovskite-type SrTiO3 nanocubes decorated reduced graphene oxide is synthesized by sonochemical method. The as-synthesized SrTiO3@RGO nanocomposite was confirmed by XRD, TEM, SEM, elemental mapping and electrochemical technique. Furthermore, surface morphological and X-ray diffraction studies revealed the formation and high loading of SrTiO3 nanocubes on reduced graphene oxide matrix. The SrTiO3@RGO nanocomposite modified electrode shows an excellent electrochemical detection towards of amino acid (tryptophan). The developed sensor was showed a wide linear range from 30 nM to 917.3 mu M and detection limit is 7.15 nM. Furthermore, the sensitivity was calculated to be 9.11 mu A mu M-1 cm(2). In addition, the proposed modified sensor is exhibited good selectivity, stability, reproducibility and repeatability. The SrTiO3@RGO catalyst modified electrode was successfully applied to tryptophan analysis in biological samples.
引用
收藏
页码:193 / 199
页数:7
相关论文
共 57 条
  • [11] Electrochemistry and voltammetric determination of L-tryptophan and L-tyrosine using a glassy carbon electrode modified with a Nafion/TiO2-graphene composite film
    Fan, Yang
    Liu, Jin-Hang
    Lu, Hai-Ting
    Zhang, Qin
    [J]. MICROCHIMICA ACTA, 2011, 173 (1-2) : 241 - 247
  • [12] Electrochemical determination of tryptophan, uric acid and ascorbic acid at a gold nanoparticles modified carbon paste electrode
    Ghoreishi, Sayed Mehdi
    Behpour, Mohsen
    Saeidinejad, Faezeh
    [J]. ANALYTICAL METHODS, 2012, 4 (08) : 2447 - 2453
  • [13] Govindasamy M., 2018, ULTRASON SONOCHEM
  • [14] Determination of oxidative stress biomarker 3-nitro-L-tyrosine using CdWO4 nanodots decorated reduced graphene oxide
    Govindasamy, Mani
    Manavalan, Shaktivel
    Chen, Shen-Ming
    Umamaheswari, Rajaji
    Chen, Tse-Wei
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2018, 272 : 274 - 281
  • [15] Graphene Oxide Nanoribbons Film Modified Screen-Printed Carbon Electrode for Real-Time Detection of Methyl Parathion in Food Samples
    Govindasamy, Mani
    Umamaheswari, Rajaji
    Chen, Shen-Ming
    Mani, Veerappan
    Su, Chaochin
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (09) : B403 - B408
  • [16] Reduced Graphene Oxide Supported Cobalt Bipyridyl Complex for Sensitive Detection of Methyl Parathion in Fruits and Vegetables
    Govindasamy, Mani
    Sakthinathan, Subramanian
    Chen, Shen-Ming
    Chiu, Te-Wei
    Sathiyan, Anandaraj
    Merlin, Johnson Princy
    [J]. ELECTROANALYSIS, 2017, 29 (08) : 1950 - 1960
  • [17] Highly sensitive determination of non-steroidal anti-inflammatory drug nimesulide using electrochemically reduced graphene oxide nanoribbons
    Govindasamy, Mani
    Mani, Veerappan
    Chen, Shen-Ming
    Maiyalagan, Thandavarayan
    Selvaraj, S.
    Chen, Tse-Wei
    Leee, Shih-Yi
    Chang, Wen-Han
    [J]. RSC ADVANCES, 2017, 7 (52) : 33043 - 33051
  • [18] Methyl parathion detection in vegetables and fruits using silver@graphene nanoribbons nanocomposite modified screen printed electrode
    Govindasamy, Mani
    Mani, Veerappan
    Chen, Shen-Ming
    Chen, Tse-Wei
    Sundramoorthy, Ashok Kumar
    [J]. SCIENTIFIC REPORTS, 2017, 7
  • [19] Simultaneous determination of dopamine and uric acid in the presence of high ascorbic acid concentration using cetyltrimethylammonium bromide-polyaniline/activated charcoal composite
    Govindasamy, Mani
    Chen, Shen-Ming
    Mani, Veerappan
    Sathiyan, Anandaraj
    Merlin, Johnson Princy
    Al-Hemaid, Fahad M. A.
    Ali, M. Ajmal
    [J]. RSC ADVANCES, 2016, 6 (102) : 100605 - 100613
  • [20] Molybdenum disulfide nanosheets coated multiwalled carbon nanotubes composite for highly sensitive determination of chloramphenicol in food samples milk, honey and powdered milk
    Govindasamy, Mani
    Chen, Shen-Ming
    Mani, Veerappan
    Devasenathipathy, Rajkumar
    Umamaheswari, Rajaji
    Santhanaraj, K. Joseph
    Sathiyan, Anandaraj
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 485 : 129 - 136