Facile sonochemical synthesis of perovskite-type SrTiO3 nanocubes with reduced graphene oxide nanocatalyst for an enhanced electrochemical detection of α-amino acid (tryptophan)

被引:89
作者
Govindasamy, Mani [1 ]
Wang, Sea-Fue [1 ]
Pan, Wei Chih [1 ]
Subramanian, Bowya [2 ,3 ]
Ramalingam, R. Jothi [4 ]
Al-lohedan, Hamad [4 ]
机构
[1] Natl Taipei Univ Technol, Dept Mat & Mineral Resources Engn, 1,Sec 3,Chung Hsiao East Rd, Taipei 106, Taiwan
[2] Natl Taipei Univ Technol, Dept Elect Engn & Comp Sci, 1,Sec 3,Chung Hsiao East Rd, Taipei 106, Taiwan
[3] KSR Coll Engn, Dept Informat Technol, Tiruchengode, Tamil Nadu, India
[4] King Saud Univ, Coll Sci, Chem Dept, Surfactant Res Chair, POB 2455, Riyadh 11451, Saudi Arabia
关键词
Sonochemical synthesis; Perovskite-type SrTiO3; Reduced graphene oxide; Electrochemical sensor; Amino acid detection; CARBON-PASTE ELECTRODE; HIGHLY SENSITIVE DETERMINATION; MICROWAVE-ASSISTED SYNTHESIS; OXIDATIVE STRESS BIOMARKER; CORE-SHELL NANOCOMPOSITE; BORON-DOPED DIAMOND; VOLTAMMETRIC DETERMINATION; METHYL PARATHION; SELECTIVE DETERMINATION; NANOPARTICLES;
D O I
10.1016/j.ultsonch.2019.04.004
中图分类号
O42 [声学];
学科分类号
070206 ; 082403 ;
摘要
In this paper, perovskite-type SrTiO3 nanocubes decorated reduced graphene oxide is synthesized by sonochemical method. The as-synthesized SrTiO3@RGO nanocomposite was confirmed by XRD, TEM, SEM, elemental mapping and electrochemical technique. Furthermore, surface morphological and X-ray diffraction studies revealed the formation and high loading of SrTiO3 nanocubes on reduced graphene oxide matrix. The SrTiO3@RGO nanocomposite modified electrode shows an excellent electrochemical detection towards of amino acid (tryptophan). The developed sensor was showed a wide linear range from 30 nM to 917.3 mu M and detection limit is 7.15 nM. Furthermore, the sensitivity was calculated to be 9.11 mu A mu M-1 cm(2). In addition, the proposed modified sensor is exhibited good selectivity, stability, reproducibility and repeatability. The SrTiO3@RGO catalyst modified electrode was successfully applied to tryptophan analysis in biological samples.
引用
收藏
页码:193 / 199
页数:7
相关论文
共 57 条
  • [1] Preparation of SrTiO3 perovskite decorated rGO and electrochemical detection of nitroaromatics
    Ahmad, Khursheed
    Mohammad, Akbar
    Mathur, Pradeep
    Mobin, Shaikh M.
    [J]. ELECTROCHIMICA ACTA, 2016, 215 : 435 - 446
  • [2] Sonochemical Synthesis of SrTiO3 Nanocrystals at Low Temperature
    Ashiri, Rouholah
    Ajami, Reza
    Moghtada, Abdolmajid
    [J]. INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2015, 12 : E202 - E206
  • [3] Measurement of Interpeptidic Cu(II) Exchange Rate Constants by Static Fluorescence Quenching of Tryptophan
    Beuning, Cheryle N.
    Mestre-Voegtle, Beatrice
    Faller, Peter
    Hureau, Christelle
    Crans, Debbie C.
    [J]. INORGANIC CHEMISTRY, 2018, 57 (09) : 4791 - 4794
  • [4] Advanced Fuel Cell Based on Perovskite La-SrTiO3 Semiconductor as the Electrolyte with Superoxide-Ion Conduction
    Chen, Gang
    Zhu, Bin
    Deng, Hui
    Luo, Yadan
    Sun, Wenkang
    Liu, Hailiang
    Zhang, Wei
    Wang, Xunying
    Qian, Yumin
    Hu, Xianwei
    Geng, Shujiang
    Kim, Jung-Sik
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (39) : 33179 - 33186
  • [5] Hierarchically structured CuFe2O4 ND@RGO composite for the detection of oxidative stress biomarker in biological fluids
    Chen, Shen-Ming
    Umamaheswari, Rajaji
    Mani, Govindasamy
    Chen, Tse-Wei
    Ali, M. Ajmal
    Fahad, Al-Hemaid M. A.
    Elshikh, M. S.
    Abul Farah, M.
    [J]. INORGANIC CHEMISTRY FRONTIERS, 2018, 5 (04): : 944 - 950
  • [6] Acetylene black paste electrode modified with graphene as the voltammetric sensor for selective determination of tryptophan in the presence of high concentrations of tyrosine
    Deng, Peihong
    Xu, Zhifeng
    Feng, Yonglan
    [J]. MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2014, 35 : 54 - 60
  • [7] Highly stable and sensitive amperometric sensor for the determination of trace level hydrazine at cross linked pectin stabilized gold nanoparticles decorated graphene nanosheets
    Devasenathipathy, Rajkumar
    Mani, Veerappan
    Chen, Shen-Ming
    Arulraj, Daneial
    Vasantha, V. S.
    [J]. ELECTROCHIMICA ACTA, 2014, 135 : 260 - 269
  • [8] Simultaneous determination of tryptophan, kynurenine, kynurenic acid and two monoamines in rat plasma by HPLC-ECD/DAD
    Du, Ting-ting
    Cui, Ting
    Qiu, Hong-mei
    Wang, Nian-ru
    Huang, Dan
    Jiang, Xin-hui
    [J]. JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2018, 158 : 8 - 14
  • [9] Dua V., 2010, Angew. Chem. Int. Ed, V122, P2200, DOI DOI 10.1002/ANGE.200905089
  • [10] Development of anode material based on La-substituted SrTiO3 perovskites doped with manganese and/or gallium for SOFC
    Escudero, M. J.
    Irvine, J. T. S.
    Daza, L.
    [J]. JOURNAL OF POWER SOURCES, 2009, 192 (01) : 43 - 50