Effect of annealing process on the phase formation in Poly(vinylidene fluoride) Thin Films

被引：42

作者：

Abdullah, Ibtisam Yahya ^{[1
]}

Yahaya, Muhammad ^{[1
]}

Jumali, Mohd Hafizuddin Haji ^{[1
]}

Shanshool, Haider Mohammed ^{[1
]}

机构：

[1] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Appl Phys, Ukm Bangi 43600, Selangor, Malaysia

来源：

2014 UKM FST POSTGRADUATE COLLOQUIUM: PROCEEDINGS OF THE UNIVERSITI KEBANGSAAN MALAYSIA, FACULTY OF SCIENCE AND TECHNOLOGY 2014 POSTGRADUATE COLLOQUIUM | 2014年 / 1614卷

关键词：

crystalline phase; piezoelectric; spin-coated; XRD; FTIR; CRYSTALLINE PHASE; TEMPERATURE; MORPHOLOGY; POLYMORPHS; TRANSITION;

D O I：

10.1063/1.4895187

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

This work reports the initial study on the effect of annealing process on the crystalline phase of poly(vinylidene fluoride) (PVDF) thin film. PVDF powder was dissolved in N,N-dimethylformamide before spin-coated onto a glass substrate to form a film. The films were annealed at 30 degrees C, 90 degrees C and 110 degrees C for 5 hrs. The crystalline phase of the powder PVDF as received was investigated by using XRD and FTIR techniques. Moreover, the crystalline phases of thin films after annealing were investigated by using the same techniques. XRD analysis showed that in powder form PVDF exists in alpha-phase. Each annealed PVDF thin films exhibited identical formation of three-phases material namely gamma (as major phase) while alpha and beta phases as the minor phases. The FTIR analysis showed that the powder form of PVDF exists in alpha and beta phases. FTIR measurement further confirmed the XRD results implying that the annealing process has no significant effect on the phase formation in PVDF films.

引用

页码：147 / 151

页数：5

共 19 条

[1] INFRARED STUDY OF PHASE-III POLY(VINYLIDENE FLUORIDE)
BACHMANN, MA
GORDON, WL
KOENIG, JL
LANDO, JB
[J]. JOURNAL OF APPLIED PHYSICS, 1979, 50 (10) : 6106 - 6112
[2] Bhatti1 Imtiaz Noor, 2013, IOSR J APPL PHYS, V4, P42
[3] Multi layer spin-coating deposition of poly(vinylidene fluoride) films for controlling thickness and piezoelectric response
Cardoso, V. F.
Minas, G.
Lanceros-Mendez, S.
[J]. SENSORS AND ACTUATORS A-PHYSICAL, 2013, 192 : 76 - 80
[4] Micro and nanofilms of poly(vinylidene fluoride) with controlled thickness, morphology and electroactive crystalline phase for sensor and actuator applications
Cardoso, V. F.
Minas, G.
Costa, C. M.
Tavares, C. J.
Lanceros-Mendez, S.
[J]. SMART MATERIALS AND STRUCTURES, 2011, 20 (08)
[5] Chen S., 2007, J APPL PHYS, V102, P104
[6] GREGORIO R, 1994, J POLYM SCI POL PHYS, V32, P859, DOI 10.1002/polb.1994.090320509
[7] Effect of crystalline phase, orientation and temperature on the dielectric properties of poly (vinylidene fluoride) (PVDF)
Gregorio, R
Ueno, EM
[J]. JOURNAL OF MATERIALS SCIENCE, 1999, 34 (18) : 4489 - 4500
[8] Morphology and phase transition of high melt temperature crystallized poly(vinylidene fluoride)
Gregorio, R
Capitao, RC
[J]. JOURNAL OF MATERIALS SCIENCE, 2000, 35 (02) : 299 - 306
[9] Effect of crystallization rate on the formation of the polymorphs of solution cast poly(vinylidene fluoride)
Gregorio, Rinaldo, Jr.
Borges, Daniel Sousa
[J]. POLYMER, 2008, 49 (18) : 4009 - 4016
[10] Application of PVDF Film Sensor to Detect Early Damage in Wind Turbine Blade Components
Huh, Y-H
Kim, J. I.
Lee, J. H.
Hong, S. G.
Park, J. H.
[J]. 11TH INTERNATIONAL CONFERENCE ON THE MECHANICAL BEHAVIOR OF MATERIALS (ICM11), 2011, 10 : 3304 - 3309

← 1 2 →