Catalytic Asymmetric Transfer Hydrogenation of Imines: Recent Advances

被引：65
|
作者：
Foubelo, Francisco [1 ,2 ]
Yus, Miguel [1 ,2 ]
机构：
[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, E-03080 Alicante, Spain
[2] Univ Alicante, Ctr Innovac Quim Avanzada ORFEO CINQA, E-03080 Alicante, Spain
来源：
CHEMICAL RECORD | 2015年 / 15卷 / 05期
关键词：
asymmetric synthesis; homogeneous catalysis; hydrogen transfer; imines; organocatalysis; DYNAMIC KINETIC RESOLUTION; BETA-AMINO ALCOHOLS; ENANTIOSELECTIVE SYNTHESIS; REDUCTIVE AMINATION; STEREOSELECTIVE-SYNTHESIS; IRON CATALYSTS; ACID; EFFICIENT; LIGANDS; KETONES;
D O I：
10.1002/tcr.201500203
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this review article recent developments in the asymmetric transfer hydrogenation of imines from 2008 up to today are presented. The main methodology involves either metal-catalyzed procedures in the presence of a chiral ligand or organocatalyzed technologies using a Hantzsch ester and a chiral BINOL-derived phosphoric acid. The most important procedures are collected, paying special attention to the application of this methodology in synthetic organic chemistry.
引用
收藏
页码：907 / 924
页数：18
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