Catalytic Asymmetric Transfer Hydrogenation of Imines: Recent Advances

被引：65
|
作者：
Foubelo, Francisco [1 ,2 ]
Yus, Miguel [1 ,2 ]
机构：
[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, E-03080 Alicante, Spain
[2] Univ Alicante, Ctr Innovac Quim Avanzada ORFEO CINQA, E-03080 Alicante, Spain
来源：
CHEMICAL RECORD | 2015年 / 15卷 / 05期
关键词：
asymmetric synthesis; homogeneous catalysis; hydrogen transfer; imines; organocatalysis; DYNAMIC KINETIC RESOLUTION; BETA-AMINO ALCOHOLS; ENANTIOSELECTIVE SYNTHESIS; REDUCTIVE AMINATION; STEREOSELECTIVE-SYNTHESIS; IRON CATALYSTS; ACID; EFFICIENT; LIGANDS; KETONES;
D O I：
10.1002/tcr.201500203
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this review article recent developments in the asymmetric transfer hydrogenation of imines from 2008 up to today are presented. The main methodology involves either metal-catalyzed procedures in the presence of a chiral ligand or organocatalyzed technologies using a Hantzsch ester and a chiral BINOL-derived phosphoric acid. The most important procedures are collected, paying special attention to the application of this methodology in synthetic organic chemistry.
引用
收藏
页码：907 / 924
页数：18
相关论文
共 50 条
  • [1] Catalytic asymmetric transfer hydrogenation of ketones: recent advances
    Foubelo, Francisco
    Najera, Carmen
    Yus, Miguel
    TETRAHEDRON-ASYMMETRY, 2015, 26 (15-16) : 769 - 790
  • [2] Recent Developments in Asymmetric Hydrogenation and Transfer Hydrogenation of Ketones and Imines through Dynamic Kinetic Resolution
    Echeverria, Pierre-Georges
    Ayad, Tahar
    Phansavath, Phannarath
    Ratovelomanana-Vidal, Virginie
    SYNTHESIS-STUTTGART, 2016, 48 (16): : 2523 - 2539
  • [3] Catalytic asymmetric transfer hydrogenation: an industrial perspective
    Cotarca, Livius
    Verzini, Massimo
    Volpicelli, Raffaella
    CHIMICA OGGI-CHEMISTRY TODAY, 2014, 32 (05) : 36 - 41
  • [4] Progress on the Catalytic Asymmetric Hydrogenation of Imines
    Wang, Dong
    Hou, Chuanjin
    Chen, Lifeng
    Liu, Xiaoning
    An, Qingda
    Hu, Xiangping
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2013, 33 (07) : 1355 - 1368
  • [5] Towards a Zinc-Catalyzed Asymmetric Hydrogenation/Transfer Hydrogenation of Imines
    Werkmeister, Svenja
    Fleischer, Steffen
    Junge, Kathrin
    Beller, Matthias
    CHEMISTRY-AN ASIAN JOURNAL, 2012, 7 (11) : 2562 - 2568
  • [6] Selected recent developments in the enantioselective reduction of imines by asymmetric transfer hydrogenation
    Roszkowski, Piotr
    Czarnocki, Zbigniew
    MINI-REVIEWS IN ORGANIC CHEMISTRY, 2007, 4 (03) : 190 - 200
  • [7] Asymmetric Transfer Hydrogenation of Stable NH Imines for the Synthesis of Enantiopure α-Chiral Primary Amines
    Zhang, Mangang
    Li, Hui
    Wu, Keqin
    Rong, Nianxin
    Lin, Shaoquan
    Yang, Hua
    Yin, Qin
    CHINESE JOURNAL OF CHEMISTRY, 2024, 42 (18) : 2211 - 2216
  • [8] A concise review on recent advances in catalytic asymmetric hydrogenation
    Behera, Priyanka
    Ramakrishna, Duggirala S.
    Chandrasekhar, Manchikanti M.
    Kothakapu, Sridhar Reddy
    CHIRALITY, 2023, 35 (08) : 477 - 497
  • [9] Recent Advances of α-Isothiocyanato Compounds in the Catalytic Asymmetric Reaction
    Han, Wen-Yong
    Zhao, Jian-Qiang
    Zuo, Jian
    Xu, Xiao-Ying
    Zhang, Xiao-Mei
    Yuan, Wei-Cheng
    ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (14-15) : 3007 - 3031
  • [10] Asymmetric Hydrogenation vs Transfer Hydrogenation in the Reduction of Cyclic Imines
    Facchetti, Giorgio
    Bucci, Raffaella
    Fuse, Marco
    Rimoldi, Isabella
    CHEMISTRYSELECT, 2018, 3 (31): : 8797 - 8800
12345