Ionic Liquids and Deep Eutectic Solvents in Natural Products Research: Mixtures of Solids as Extraction Solvents

被引：396

作者：

Dai, Yuntao ^{[1
]}

van Spronsen, Jaap ^{[2
]}

Witkamp, Geert-Jan ^{[2
]}

Verpoorte, Robert ^{[1
]}

Choi, Young Hae ^{[1
]}

机构：

[1] Leiden Univ, Inst Biol, Nat Prod Lab, NL-2300 RA Leiden, Netherlands

[2] Delft Univ Technol, Dept Biotechnol, Delft, Netherlands

来源：

JOURNAL OF NATURAL PRODUCTS | 2013年 / 76卷 / 11期

关键词：

MICROWAVE-ASSISTED EXTRACTION; SELECTIVE EXTRACTION; CARBON-DIOXIDE; GREEN SOLVENTS; ESSENTIAL OIL; ACID; DISSOLUTION; CELLULOSE; CHLORIDE; C-13;

D O I：

10.1021/np400051w

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Mixtures of solid chemicals may become liquid under certain conditions. These liquids are characterized by the formation of strong ionic (ionic liquids) or hydrogen bonds (deep eutectic solvents). Due to their extremely low vapor pressure, they are now widely used in polymer chemistry and synthetic organic chemistry, yet little attention has been paid to their use as extraction solvents of natural products. This review summarizes the preparation of ionic liquids and deep eutectic solvents with natural product components and recent progress in their applications to the extraction and analysis of natural products as well as the recovery of extracted compounds from their extracts. Additionally, various factors affecting extraction features of ionic liquids and deep eutectic solvents, as well as potential useful technologies including microwave and ultrasound to increase the extraction efficiency, are discussed.

引用

页码：2162 / 2173

页数：12

共 102 条

[1] Extraction of glycerol from biodiesel into a eutectic based ionic liquid [J].

Abbott, Andrew P. ;

Cullis, Paul M. ;

Gibson, Manda J. ;

Harris, Robert C. ;

Raven, Emma .

GREEN CHEMISTRY, 2007, 9 (08) :868-872

[2] Application of hole theory to define ionic liquids by their transport properties [J].

Abbott, Andrew P. ;

Harris, Robert C. ;

Ryder, Karl S. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (18) :4910-4913

[3] Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].

Abbott, AP ;

Boothby, D ;

Capper, G ;

Davies, DL ;

Rasheed, RK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147

[4] Novel solvent properties of choline chloride/urea mixtures [J].

Abbott, AP ;

Capper, G ;

Davies, DL ;

Rasheed, RK ;

Tambyrajah, V .

CHEMICAL COMMUNICATIONS, 2003, (01) :70-71

[5] Extraction of polysaccharides from bran with phosphonate or phosphinate-derived ionic liquids under short mixing time and low temperature [J].

Abe, Mitsuru ;

Fukaya, Yukinobu ;

Ohno, Hiroyuki .

GREEN CHEMISTRY, 2010, 12 (07) :1274-1280

[6] Extraction and high performance liquid chromatographic determination of 3-indole butyric acid in pea plants by using imidazolium-based ionic liquids as extractant [J].

Absalan, Godratollah ;

Akhond, Morteza ;

Sheikhian, Leila .

TALANTA, 2008, 77 (01) :407-411

[7] Green Chemistry: Principles and Practice [J].

Anastas, Paul ;

Eghbali, Nicolas .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :301-312

[8] Characterizing ionic liquids on the basis of multiple solvation interactions [J].

Anderson, JL ;

Ding, J ;

Welton, T ;

Armstrong, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) :14247-14254

[9] Synthesis of chiral ionic liquids from natural amino acids [J].

Bao, WL ;

Wang, ZM ;

Li, YX .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (02) :591-593

[10] Ionic liquids in separation techniques [J].

Berthod, A. ;

Ruiz-Angel, Mt ;

Carda-Broch, S. .

JOURNAL OF CHROMATOGRAPHY A, 2008, 1184 (1-2) :6-18

← 1 2 3 4 5 6 7 8 9 10 →