Effects of Antimony Addition to Perovskite-type CH3NH3PbI3 Photovoltaic Devices

被引:57
作者
Oku, Takeo [1 ]
Ohishi, Yuya [1 ]
Suzuki, Atsushi [1 ]
机构
[1] Univ Shiga Prefecture, Dept Mat Sci, 2500 Hassaka, Hikone, Shiga 5228533, Japan
基金
日本科学技术振兴机构;
关键词
SOLAR-CELLS; HALIDE; LAYERS;
D O I
10.1246/cl.150984
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Effects of SbI3 addition to CH3NH3PbI3 precursor solutions on the photovoltaic properties were investigated. TiO2/CH3NH3Pb1-xSbxI3-based photovoltaic devices were fabricated in air, and formation of a perovskite-type structure was confirmed by X-ray diffraction. The conversion efficiencies were improved by adding a small amount of Sb, and formation of PbI2 was suppressed by the Sb addition.
引用
收藏
页码:134 / 136
页数:3
相关论文
共 20 条
[1]   Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications [J].
Baikie, Tom ;
Fang, Yanan ;
Kadro, Jeannette M. ;
Schreyer, Martin ;
Wei, Fengxia ;
Mhaisalkar, Subodh G. ;
Graetzel, Michael ;
White, Tim J. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5628-5641
[2]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[3]   Lead-free solid-state organic-inorganic halide perovskite solar cells [J].
Hao, Feng ;
Stoumpos, Constantinos C. ;
Duyen Hanh Cao ;
Chang, Robert P. H. ;
Kanatzidis, Mercouri G. .
NATURE PHOTONICS, 2014, 8 (06) :489-494
[4]   6.5% efficient perovskite quantum-dot-sensitized solar cell [J].
Im, Jeong-Hyeok ;
Lee, Chang-Ryul ;
Lee, Jin-Wook ;
Park, Sang-Won ;
Park, Nam-Gyu .
NANOSCALE, 2011, 3 (10) :4088-4093
[5]   Compositional engineering of perovskite materials for high-performance solar cells [J].
Jeon, Nam Joong ;
Noh, Jun Hong ;
Yang, Woon Seok ;
Kim, Young Chan ;
Ryu, Seungchan ;
Seo, Jangwon ;
Seok, Sang Il .
NATURE, 2015, 517 (7535) :476-+
[6]   Structural study on cubic-tetragonal transition of CH3NH3PbI3 [J].
Kawamura, Y ;
Mashiyama, H ;
Hasebe, K .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2002, 71 (07) :1694-1697
[7]   Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells [J].
Kojima, Akihiro ;
Teshima, Kenjiro ;
Shirai, Yasuo ;
Miyasaka, Tsutomu .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (17) :6050-+
[8]   Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites [J].
Lee, Michael M. ;
Teuscher, Joel ;
Miyasaka, Tsutomu ;
Murakami, Takurou N. ;
Snaith, Henry J. .
SCIENCE, 2012, 338 (6107) :643-647
[9]   Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques [J].
Liu, Dianyi ;
Kelly, Timothy L. .
NATURE PHOTONICS, 2014, 8 (02) :133-138
[10]   Efficient planar heterojunction perovskite solar cells by vapour deposition [J].
Liu, Mingzhen ;
Johnston, Michael B. ;
Snaith, Henry J. .
NATURE, 2013, 501 (7467) :395-+