Continuous and Localized Mn Implantation of ZnO

被引:16
作者
Sanz, R. [1 ]
Jensen, J. [2 ]
Gonzalez-Diaz, G. [3 ]
Martinez, O. [4 ]
Vazquez, M. [1 ]
Hernandez-Velez, M. [1 ,5 ]
机构
[1] CSIC, Inst Ciencia Mat Madrid, Madrid 28049, Spain
[2] Linkoping Univ, IFM, Dept Phys Chem & Biol, Thin Film Phys Div, S-58183 Linkoping, Sweden
[3] Univ Complutense Madrid, Dept Fis Aplicada Elect & Elect 3, Madrid, Spain
[4] Univ Valladolid, Dept Fis Mat Condensada, Optronlab Grp, E-47011 Valladolid, Spain
[5] Univ Autonoma Madrid, E-28049 Madrid, Spain
来源
NANOSCALE RESEARCH LETTERS | 2009年 / 4卷 / 08期
关键词
Ion implantation; Nanoporous anodic alumina; Magnetic semiconductors; Magnetic properties; ZnO; FERROMAGNETISM; FABRICATION; NANOWIRES; ARRAYS; TIO2;
D O I
10.1007/s11671-009-9327-5
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We present results derived from continuous and localized 35 keV Mn-55(+) ion implantations into ZnO. Localized implantations were carried out by using self-ordered alumina membranes as masks leading to ordered arrays of implanted volumes on the substrate surfaces. Defects and vacancies in the small implantation volumes of ZnO were generated due to the implantation processes besides the creation of new phases. Rapid thermal annealing was applied in the case of continuous implantation. The samples were characterized by HRSEM, GIXRD, Raman spectroscopy and RBS/C. Magnetic characterization of the samples pointed out appreciable differences among the samples obtained by the different implantation methods. This fact was mainly attributed to the different volume/surface ratios present in the implanted zones as well as to the increase of Mn atom concentrations along the grain frontiers in the nanostructured surfaces. The samples also showed a ferromagnetic transition phase at temperature value higher than room temperature.
引用
收藏
页码:878 / 887
页数:10
相关论文
共 30 条
[1]   Isotopic study of the nitrogen-related modes in N+-implanted ZnO [J].
Artus, L. ;
Cusco, R. ;
Alarcon-Llado, E. ;
Gonzalez-Diaz, G. ;
Martil, I. ;
Jimenez, J. ;
Wang, B. ;
Callahan, M. .
APPLIED PHYSICS LETTERS, 2007, 90 (18)
[2]   Stable cubic spinels in the Zn-Mn-O system in air [J].
Blasco, J. ;
Garcia, J. .
JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (07) :2199-2205
[3]   Vibrational spectroscopy of bulk and supported manganese oxides [J].
Buciuman, F ;
Patcas, F ;
Craciun, R ;
Zahn, DRT .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (01) :185-190
[4]   RESONANT RAMAN-SCATTERING IN ZNO [J].
CALLEJA, JM ;
CARDONA, M .
PHYSICAL REVIEW B, 1977, 16 (08) :3753-3761
[5]   Correlation between Mn oxidation state and magnetic behavior in Mn/ZnO multilayers prepared by sputtering [J].
Cespedes, E. ;
Garcia-Lopez, J. ;
Garcia-Hernandez, M. ;
De Andres, A. ;
Prieto, C. .
JOURNAL OF APPLIED PHYSICS, 2007, 102 (03)
[6]   Production and recovery of defects in phosphorus-implanted ZnO [J].
Chen, ZQ ;
Kawasuso, A ;
Xu, Y ;
Naramoto, H ;
Yuan, XL ;
Sekiguchi, T ;
Suzuki, R ;
Ohdaira, T .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (01)
[7]   Temperature dependence of raman scattering in ZnO [J].
Cusco, Ramon ;
Alarcon-Llado, Esther ;
Ibanez, Jordi ;
Artus, Luis ;
Jimenez, Juan ;
Wang, Buguo ;
Callahan, Michael J. .
PHYSICAL REVIEW B, 2007, 75 (16)
[8]  
DARSHAN C, 2005, NAT MATER, V3, P709
[9]   Zener model description of ferromagnetism in zinc-blende magnetic semiconductors [J].
Dietl, T ;
Ohno, H ;
Matsukura, F ;
Cibert, J ;
Ferrand, D .
SCIENCE, 2000, 287 (5455) :1019-1022
[10]   Interface double-exchange ferromagnetism in the Mn-Zn-O system:: New class of biphase magnetism -: art. no. 217206 [J].
García, MA ;
Ruiz-González, ML ;
Quesada, A ;
Costa-Krämer, JL ;
Fernández, JF ;
Khatib, SJ ;
Wennberg, A ;
Caballero, AC ;
Martín-González, MS ;
Villegas, M ;
Briones, F ;
González-Calbet, JM ;
Hernando, A .
PHYSICAL REVIEW LETTERS, 2005, 94 (21)