Reactions of endohedral metallofullerenes with azomethine ylides: an efficient route toward metallofullerene-pyrrolidines

被引：11

作者：

Feng, L ^{[1
]}

Lu, X ^{[1
]}

He, XR ^{[1
]}

Shi, ZJ ^{[1
]}

Gu, ZN ^{[1
]}

机构：

[1] Beijing Univ, Dept Chem, Beijing 100871, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 09期

基金：

中国国家自然科学基金;

关键词：

cycloaddition; endohedral metallofullerenes; fullerenes; fulleropyrrolidines;

D O I：

10.1016/j.inoche.2004.07.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Azomethine ylides, generated from the reactions of different aldehydes (RCHO) 1a-d with sarcosine, reacted with endohedral metallofullerenes M@C-82 (M = Gd, Y) affording multi-substituted metallofulleropyrrolidines. The formation of these derivatives was confirmed by matrix assisted laser desorption/ionization (MALDI) time-of-flight (TOF) mass spectrometry and some of them were isolated by recycling HPLC. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1010 / 1013

页数：4

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