Characteristics of intermolecular transfer of sterically screened protons of octaphenyl-substituted tetraazaporphyrins in the N-base-benzene system

被引:0
|
作者
Petrov, OA [1 ]
机构
[1] Ivanovo State Univ Chem Technol, Ivanovo, Russia
来源
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2002年 / 76卷 / 09期
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Acid-base interactions of octa(p-nitrophenyl)tetraazaporphyrin and octa(p-bromophenyl)tetraazaporphyrin with tributylamine and tert-butylamine in benzene were studied. The influence of electronic and steric factors on the kinetics and mechanism of intermolecular transfer of NH protons of octaphenyl-substituted tetraazaporphyrins was considered. The structure and stability of the resulting proton-transfer complexes were discussed.
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页码:1423 / 1428
页数:6
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