Electrochemical deposition of carbon in LiCl-NaCl-Na2CO3 melts

被引：51

作者：

Ge, Jianbang ^{[1
]}

Wang, Shuai ^{[1
]}

Hu, Liwen ^{[1
]}

Zhu, Jun ^{[1
]}

Jiao, Shuqiang ^{[1
]}

机构：

[1] Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China

来源：

CARBON | 2016年 / 98卷

基金：

中国国家自然科学基金;

关键词：

ANODE MATERIALS; MOLTEN-SALTS; FILMS; CO2; ELECTRODEPOSITION; ELECTROLYSIS; CONVERSION; CAPTURE; ION; NANOTUBES;

D O I：

10.1016/j.carbon.2015.11.065

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Carbon deposition on a W cathode during the electrolysis was performed in molten LiCl-NaCl-Na2CO3 under CO2 atmosphere. The electrochemical process was investigated by cyclic voltammetry on the glass carbon electrode. The minimum energy consumption is 20.1 kWh for 1 kg of carbon. Constant voltage electrolysis combined with a real-time resolution mass spectrum demonstrated the absence of the formation of carbon monoxide even at 800 degrees C. The carbon products deposited at different electrolysis conditions were composed of amorphous carbon and mainly comprised of quasi-spherical carbon particles accompanied by small amounts of wire-like carbon. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：649 / 657

页数：9

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