Synthesis and X-ray Crystal Structures of Ru3(CO)9(μ-arphos)(L) [L = AsPh3, As(m-C6H4Me)3, As(p-C6H4Me)3]

被引：1
|
作者：
Sirat, Siti Syaida [1 ]
Bin Shawkataly, Omar [1 ]
机构：
[1] Univ Sains Malaysia, Sch Distance Educ, Chem Sci Programme, George Town 11800, Malaysia
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2019年 / 645卷 / 09期
关键词：
Triruthenium; Metal cluster; Group; 15; ligand; X-ray diffraction; LIGAND-SUBSTITUTED DERIVATIVES; CLUSTER CHEMISTRY; ELECTRONIC-PROPERTIES; RU3(CO)12; STEREOCHEMISTRY; COMPLEXES; P(OCH2CF3)3; OS3(CO)12; PPH(OME)2; PME2PH;
D O I：
10.1002/zaac.201900013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new triruthenium clusters, Ru-3(CO)(9)(mu -arphos)AsPh3 (1), Ru-3(CO)(9)(mu -arphos)As(m-C6H4Me)(3) (2), and Ru-3(CO)(9)(mu -arphos)As(p-C6H4Me)(3) (3) were synthesized via thermal reactions of Ru-3(CO)(10)(mu -arphos) with different tertiary arsine ligands [AsPh3, As(m-C6H4Me)(3), As(p-C6H4Me)(3)]. All these complexes were fully characterized by elemental analysis, FT-IR, NMR spectroscopy, and single-crystal X-ray diffraction.
引用
收藏
页码：683 / 687
页数：5
相关论文
共 50 条
  • [41] Second sphere coordination in orthonitrophenolate binding: Synthesis, biological, cytotoxic and X-ray structural studies of [Co(bpy)2CO3](C6H4NO3)•3H2O
    Arora, Santosh
    Talwar, Dinesh
    Singh, Manjeet
    Sahoo, Subash C.
    Sharma, Rohit
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1199
  • [42] Structural studies of diorganotin(IV) sulfonates: The synthesis of [(n-C4H9)2Sn{OSO2C6H3(CH3)2-2,5}2] and [(n-C4H9)2Sn{OSO2R)2 • 2(hexamethylphosphoric triamide)] [R = CH3, 4-C6H4CH3, 2,5-C6H3(CH3)2, 2,4,6-C6H2(CH3)3] and crystal structures of [(n-C4H9)2Sn(μ-OH)(OSO2C6H3(CH3)2-2,5)]2 and (n-C4H9)2Sn{OSO2R)2 • 2(hexamethylphosphoric triamide)] [R = 4-C6H4CH3, 2,5-C6H3(CH3)2, 2,4,6-C6H2(CH3)3]
    Kapoor, Ramesh
    Gupta, Anand
    Venugopalan, Paloth
    Pannu, Ajay Pal Singh
    Hundal, Maninder Singh
    Kapoor, Pratibha
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (05) : 623 - 629
  • [43] New trisubstituted triruthenium carbonyl cluster containing mixed P/As ligands: synthesis, characterization, crystal structure, and Hirshfeld surface analysis of Ru3(CO)9(μ-Ph2P(CH2)4PPh2)(AsPh3)
    Sirat, Siti Syaida
    Arshad, Suhana
    Bin Shawkataly, Omar
    INORGANIC AND NANO-METAL CHEMISTRY, 2024,
  • [44] The first synthesis, isolation and x-ray structure of a phosphonium phosphide, (Ph3PMe)+{[C6H2(CF3)3-2,4,6]2P}-
    Davidson, MG
    Dillon, KB
    Howard, JAK
    Lamb, S
    Roden, MD
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 550 (1-2) : 481 - 484
  • [45] Unsymmetrical alkyne binding to a triruthenium centre: Oxidative-addition of diphenyl ditelluride to the furyne cluster [Ru3(CO)7(μ-H)(μ3-η2-C4H2O){μ-P(C4H3O)2}(μ-dppm)]
    Ghosh, Shishir
    Hogarth, Graeme
    Kabir, Shariff E.
    Nordlander, Ebbe
    Salassa, Luca
    Tocher, Derek A.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (10) : 1982 - 1989
  • [46] Tris(fluorophenyl)antimony Bis(arenesulfonates) (3-FC6H4)3Sb(OSO2R)2 (R = Ph, C6H3Me2-2,4) and (4-FC6H4)3Sb(OSO2Ph)2: Synthesis and Structures
    Sharutin, V. V.
    Sharutina, O. K.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2022, 48 (05) : 311 - 317
  • [47] High versatility of 3,4-dimethyl-1-phenyl-phosphole and 3-methyl-1-phenyl-phosphole as ligands in the reaction with [Re2(CO)8(CH3CN)2] and [Ru3(CO)12]: X-ray structures of [Re2(CO)7(η1:η2:η2-PhPC4H2Me2)], [Re2(CO)7(η1:η2:η2-PhPC4H3Me)] and [Ru2(CO)4(PhPC4H3Me)2]
    Otero, Yomaira
    Arce, Alejandro
    De Sanctis, Ysaura
    Machado, Ruben
    Goite, Maria C.
    Gonzalez, Teresa
    Briceno, Alexander
    INORGANICA CHIMICA ACTA, 2013, 404 : 77 - 81
  • [48] Investigating intermolecular bonding in diphenylbismuth(III) chalcogenolates: X-ray crystal structures of (Ph2BiSR′) (R′ = Ph; 2,6-Me2C6H3)
    Briand, Glen G.
    Decken, Andreas
    Hunter, Nicole M.
    Lee, Graham M.
    Melanson, Jennifer A.
    Owen, Evan M.
    POLYHEDRON, 2012, 31 (01) : 796 - 800
  • [49] Synthesis and crystal structure of [3,5-(CH3O)2C6H3NH3]4P4O12•4H2O
    Aloui, Z
    Abid, S
    Rzaigui, M
    MATERIALS RESEARCH BULLETIN, 2002, 37 (04) : 697 - 703
  • [50] Mixed-dicyclopentadienyl niobium and tantalum complexes: Synthesis and reactivity X-ray molecular structures of Ta(eta(5)-C(5)Me(5))(eta(5)-C(5)H(4)SiMe(3))Cl-2 and Ta(eta(5)-C(5)Me(5)){eta(5)-C5H3(SiMe(3))(2)}H-3
    Castro, A
    Gomez, M
    GomezSal, P
    Manzanero, A
    Royo, P
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 518 (1-2) : 37 - 46
12345