Synthesis and X-ray Crystal Structures of Ru3(CO)9(μ-arphos)(L) [L = AsPh3, As(m-C6H4Me)3, As(p-C6H4Me)3]

被引：1
|
作者：
Sirat, Siti Syaida [1 ]
Bin Shawkataly, Omar [1 ]
机构：
[1] Univ Sains Malaysia, Sch Distance Educ, Chem Sci Programme, George Town 11800, Malaysia
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2019年 / 645卷 / 09期
关键词：
Triruthenium; Metal cluster; Group; 15; ligand; X-ray diffraction; LIGAND-SUBSTITUTED DERIVATIVES; CLUSTER CHEMISTRY; ELECTRONIC-PROPERTIES; RU3(CO)12; STEREOCHEMISTRY; COMPLEXES; P(OCH2CF3)3; OS3(CO)12; PPH(OME)2; PME2PH;
D O I：
10.1002/zaac.201900013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new triruthenium clusters, Ru-3(CO)(9)(mu -arphos)AsPh3 (1), Ru-3(CO)(9)(mu -arphos)As(m-C6H4Me)(3) (2), and Ru-3(CO)(9)(mu -arphos)As(p-C6H4Me)(3) (3) were synthesized via thermal reactions of Ru-3(CO)(10)(mu -arphos) with different tertiary arsine ligands [AsPh3, As(m-C6H4Me)(3), As(p-C6H4Me)(3)]. All these complexes were fully characterized by elemental analysis, FT-IR, NMR spectroscopy, and single-crystal X-ray diffraction.
引用
收藏
页码：683 / 687
页数：5
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