Synthesis and X-ray Crystal Structures of Ru3(CO)9(μ-arphos)(L) [L = AsPh3, As(m-C6H4Me)3, As(p-C6H4Me)3]

被引：1

作者：

Sirat, Siti Syaida ^{[1
]}

Bin Shawkataly, Omar ^{[1
]}

机构：

[1] Univ Sains Malaysia, Sch Distance Educ, Chem Sci Programme, George Town 11800, Malaysia

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2019年 / 645卷 / 09期

关键词：

Triruthenium; Metal cluster; Group; 15; ligand; X-ray diffraction; LIGAND-SUBSTITUTED DERIVATIVES; CLUSTER CHEMISTRY; ELECTRONIC-PROPERTIES; RU3(CO)12; STEREOCHEMISTRY; COMPLEXES; P(OCH2CF3)3; OS3(CO)12; PPH(OME)2; PME2PH;

D O I：

10.1002/zaac.201900013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new triruthenium clusters, Ru-3(CO)(9)(mu -arphos)AsPh3 (1), Ru-3(CO)(9)(mu -arphos)As(m-C6H4Me)(3) (2), and Ru-3(CO)(9)(mu -arphos)As(p-C6H4Me)(3) (3) were synthesized via thermal reactions of Ru-3(CO)(10)(mu -arphos) with different tertiary arsine ligands [AsPh3, As(m-C6H4Me)(3), As(p-C6H4Me)(3)]. All these complexes were fully characterized by elemental analysis, FT-IR, NMR spectroscopy, and single-crystal X-ray diffraction.

引用

页码：683 / 687

页数：5

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