Palladium-Catalyzed Carbonylative Transformation of C(sp3)-X Bonds

被引：161

作者：

Wu, Lipeng ^{[1
]}

Fang, Xianjie ^{[1
]}

Liu, Qiang ^{[1
]}

Jackstell, Ralf ^{[1
]}

Beller, Matthias ^{[1
]}

Wu, Xiao-Feng ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany

来源：

ACS CATALYSIS | 2014年 / 4卷 / 09期

关键词：

palladium catalyst; carbonylation; C(sp(3))-X bonds; cross-coupling; carbon monoxide; C-H BONDS; TRISULFONATED TRIPHENYLPHOSPHINE COMPLEXES; NOBLE METAL COMPOUNDS; ORGANIC ALLYL MOIETIES; BETA-KETO-ESTERS; CARBON-MONOXIDE; BETA; GAMMA-UNSATURATED ESTERS; ARYL HALIDES; OXIDATIVE CARBONYLATION; COUPLING REACTIONS;

D O I：

10.1021/cs500922x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

During the last 50 years, the palladium-catalyzed carbonylation reactions underwent continuous development. Apart from carbonylation of aromatic (pseudo)-halide and alkene (C-sp(2)) compounds, the use of C(sp(3))-X compounds such as allyl compounds, benzyl compounds, and aliphatic alkanes have become the most useful tool for the synthesis of beta,gamma-unsaturated carbonyl compounds, aliphatic carboxylic acid, and their derivatives. The recently budding development in the area of palladium-catalyzed C(sp(3))-X (especially X = H) activation makes us feel it necessary to file a summary on the past, current contributions, and a prospective outlook on the palladium-catalyzed carbonylative transformation of C(sp(3)) X bonds, which is the focus of this review.

引用

页码：2977 / 2989

页数：13

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