Complex formation of copper(II) ions with galactaric acid

被引：1

作者：

Bolotin, SN ^{[1
]}

Frolov, VY ^{[1
]}

Panyushkin, VT ^{[1
]}

机构：

[1] Kuban State Univ, Krasnodar 350751, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2004年 / 74卷 / 02期

关键词：

D O I：

10.1023/B:RUGC.0000025505.41339.70

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complex formation of copper(II) ions with the galactarate ion [Gala](2-) in aqueous solution was studied by means of potentiometric titration. Stability constants of the [CuGala] and [Cu(Gala)(2)](2-) complexes were deter-mined. A complex compound was synthesized electrochemically and isolated from a DMSO solution containing a copper(II) salt and galactaric acid, and its composition was determinded. The structure of the complex was determined by ESR.

引用

页码：219 / 221

页数：3

共 10 条

[1]

BOGDASHEV NN, 1976, ZH OBSHCH KHIM+, V46, P675

[2]

*NISIT, STAND REF DAT 46 CRI

[3]

Panyushkin VT, 1995, ZH NEORG KHIM+, V40, P287

[4]

PANYUSHKIN VT, 1999, PRIMENENIE METODA M