Preparation of novel poly(aryleneamine)s by palladium complex catalyzed polycondensation of dibromobenzenes with diamines

被引:49
作者
Kanbara, T
Honma, A
Hasegawa, K
机构
[1] Dept. of Chem. and Biochem. Eng., Faculty of Engineering, Toyama University, Toyama 930
关键词
D O I
10.1246/cl.1996.1135
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of aryl dibromides with secondary diamines proceeds smoothly in the presence of a stoichiometric base such as NaOtBu and a catalytic amount of palladium complex, PdCl2(P(o-tolyl)(3))(2) (P(o-tolyl)(3) = tri-o-tolylphosphine), in toluene to give the corresponding new poly(aryleneamine)s.
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页码:1135 / 1136
页数:2
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