Earth-abundant hydrogen evolution electrocatalysts

被引：653

作者：

McKone, James R. ^{[1
,2
]}

Marinescu, Smaranda C. ^{[1
,2
]}

Brunschwig, Bruce S. ^{[1
,2
]}

Winkler, Jay R. ^{[1
,2
]}

Gray, Harry B. ^{[1
,2
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA

[2] CALTECH, Beckman Inst, Pasadena, CA 91125 USA

来源：

CHEMICAL SCIENCE | 2014年 / 5卷 / 03期

基金：

美国国家科学基金会;

关键词：

EFFICIENT INDUSTRIAL-PRODUCTION; COBALT DIGLYOXIME CATALYSTS; ALKALINE WATER ELECTROLYSIS; ACTIVE-SITE; NI-MO; NICKEL-MOLYBDENUM; H-2; PRODUCTION; ALLOY COATINGS; MOLECULAR ELECTROCATALYSTS; ELECTROCHEMICAL REACTIONS;

D O I：

10.1039/c3sc51711j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Splitting water to hydrogen and oxygen is a promising approach for storing energy from intermittent renewables, such as solar power. Efficient, scalable solar-driven electrolysis devices require active electrocatalysts made from earth-abundant elements. In this mini-review, we discuss recent investigations of homogeneous and heterogeneous hydrogen evolution electrocatalysts, with emphasis on our own work on cobalt and iron complexes and nickel-molybdenum alloys.

引用

页码：865 / 878

页数：14

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