Earth-abundant hydrogen evolution electrocatalysts

被引：652
作者：
McKone, James R. [1 ,2 ]
Marinescu, Smaranda C. [1 ,2 ]
Brunschwig, Bruce S. [1 ,2 ]
Winkler, Jay R. [1 ,2 ]
Gray, Harry B. [1 ,2 ]
机构：
[1] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA
[2] CALTECH, Beckman Inst, Pasadena, CA 91125 USA
来源：
CHEMICAL SCIENCE | 2014年 / 5卷 / 03期
基金：
美国国家科学基金会;
关键词：
EFFICIENT INDUSTRIAL-PRODUCTION; COBALT DIGLYOXIME CATALYSTS; ALKALINE WATER ELECTROLYSIS; ACTIVE-SITE; NI-MO; NICKEL-MOLYBDENUM; H-2; PRODUCTION; ALLOY COATINGS; MOLECULAR ELECTROCATALYSTS; ELECTROCHEMICAL REACTIONS;
D O I：
10.1039/c3sc51711j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Splitting water to hydrogen and oxygen is a promising approach for storing energy from intermittent renewables, such as solar power. Efficient, scalable solar-driven electrolysis devices require active electrocatalysts made from earth-abundant elements. In this mini-review, we discuss recent investigations of homogeneous and heterogeneous hydrogen evolution electrocatalysts, with emphasis on our own work on cobalt and iron complexes and nickel-molybdenum alloys.
引用
收藏
页码：865 / 878
页数：14
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