Mathematical description of ion transport in membrane systems

被引:34
作者
Nikonenko, V
Zabolotsky, V
Larchet, C
Auclair, B
Pourcelly, G
机构
[1] Kuban State Univ, Dept Chem Phys, Krasnodar 350040, Russia
[2] Univ Paris 12, IUT, Lab Mat Echangeuses Ions, F-94000 Creteil, France
[3] Univ Montpellier 2, Inst Europeen Membranes, F-34095 Montpellier, France
关键词
mathematical modelling; ion transport; membrane; irreversible thermodynamics; diffusion layer; concentration polarisation;
D O I
10.1016/S0011-9164(02)00611-2
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A review of works resulting in development of a hierarchic system of mathematical models is presented. Different scales of ion transport are considered: 1) in the membrane, where. two approaches are used, the irreversible thermodynamics and modelling of the membrane material, the last permits to link physicochemical properties with structure-kinetic parameters of the membrane; 2) in a three-layer system composed of a membrane with two adjoining diffusion layers; and 3) in an electrodialysis 2D cell, where the differential equation of convective diffusion is used.
引用
收藏
页码:369 / 374
页数:6
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