Nonisothermal sintering of Cr2AlC powder

被引:12
作者
Rajkumar, Yembadi [1 ]
Rahul, Bapurao [1 ]
Akash, Puppala Ananth [1 ]
Panigrahi, Bharat [1 ]
机构
[1] Indian Inst Technol Hyderabad, Dept Mat Sci & Met Engn, Sangareddy, Telangana, India
关键词
Activation energy; Dilatometer; MAX Phase; Powder; Sintering; MECHANICAL-PROPERTIES; AL-C; MAX PHASES; CERAMICS; OXIDATION; BEHAVIOR; DIFFUSION; CORROSION; TI3ALC2;
D O I
10.1111/ijac.12617
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This work studies the sintering behavior of ultrafine powder of Cr2AlC compound during nonisothermal heating using a dilatometer. Sample exhibits relatively slower densification under pressureless condition where relative density increased from about 61% (green compact) to about 73% during heating up to 1350 degrees C. Axial shrinkage data were analyzed through the volume diffusion and grain boundary diffusion-based sintering models. Estimated activation energy of sintering (352 kJ/mol) for volume diffusion mechanism, was found to be closely matching with the reported activation energy of chromium diffusivity, indicating volume diffusion as a controlling mechanism and chromium as a major diffuser in Cr2AlC.
引用
收藏
页码:63 / 67
页数:5
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