Synthesis, structure and magnetic property of a 2D grid-like copper(II) complex with end-on azido and pyrazine bridges

被引：16

作者：

Dong, Wen

Yan Ouyang

Liao, Dai-Zheng ^{[1
]}

Yan, Shi-Ping

Cheng, Peng

Jiang, Zong-Hui

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Guangzhou Univ, Dept Chem, Guangzhou 510045, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 10期

基金：

中国国家自然科学基金;

关键词：

copper(II) complex; azido and pyz bridges; crystal structure; magnetic property;

D O I：

10.1016/j.ica.2006.03.040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 2D grid-like copper(II) complex [Cu(N-3)(2)(pyz)](pyz = pyrazine) (1) has been synthesized and characterized by single crystal X-ray analysis and magnetic measurements. The 2D grid-like network of 1 consists of 1D chain of Cu-pyz units connected by end-on azido bridge. 1 crystallizes in the monoclinic space group C2 with a = 15.148(6) angstrom, b = 6.877(2) angstrom, c = 3.4591(12) angstrom and Z = 2. The magnetic investigation showed the presence of an antiferromagnetic interaction between the copper(II) ions mainly mediated through pyrazine bridge. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：3363 / 3366

页数：4

共 29 条

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