Synthesis of clickable amphiphilic polysaccharides as nanoscopic assemblies

被引：7

作者：

Fu, Liye ^{[1
]}

Li, Lingyao ^{[1
]}

Wang, Jun ^{[1
]}

Knickelbein, Kyle ^{[2
]}

Zhang, Lin ^{[2
]}

Milligan, Ian ^{[1
]}

Xu, Yi ^{[1
]}

O'Hara, Kylie ^{[1
]}

Bitterman, Lindsay ^{[1
]}

Du, Wenjun ^{[1
]}

机构：

[1] Cent Michigan Univ, Dept Chem Sci Adv Mat, Mt Pleasant, MI 48858 USA

[2] Univ Pittsburgh, Dept Pharmacol & Chem Biol, Pittsburgh, PA 15213 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 84期

关键词：

RING-OPENING POLYMERIZATION; CHEMICAL-SYNTHESIS; BLOCK-COPOLYMERS; EFFICIENT SYNTHESIS; NANOPARTICLES; DELIVERY; DERIVATIVES; CHEMISTRY; POLYMERS; GLUCOSE;

D O I：

10.1039/c4cc06343k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of clickable polysaccharides was achieved by using alkynylated 1,6-anhydro glucopyranose as a monomer and BF3 center dot OEt2 as an effective catalyst. Subsequent click conjugation with polyethylene glycol (PEG) afforded PEG-grafted polysaccharides in nearly quantitative efficiency.

引用

页码：12742 / 12745

页数：4

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