Efficient, solvent-free hydrogenation of α-angelica lactone catalysed by Ru/C at atmospheric pressure and room temperature

被引：33
作者：
Al-Shaal, Mohammad G. [1 ]
Hausoul, Peter J. C. [1 ]
Palkovits, Regina [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52074 Aachen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 71期
关键词：
METHYLENE-GAMMA-BUTYROLACTONE; TRANSPORTATION FUELS; LEVULINIC ACID; VALEROLACTONE; CONVERSION; BIOMASS; 4-PENTEN-4-OLIDES; CHEMICALS; PATHWAYS; PLATFORM;
D O I：
10.1039/c4cc03970j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrogenation of alpha-angelica lactone was investigated over Ru/C. A mild protocol was developed, which resulted in full conversion and 96% selectivity toward gamma-valerolactone. The reaction network was investigated and alpha-angelica lactone was employed in the one-pot conversion into 2-methyltetrahydrofuran, demonstrating its superiority as a platform molecule in potential biorefinery schemes.
引用
收藏
页码：10206 / 10209
页数：4
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