Investigations into the characteristics of oils produced from co-pyrolysis of biomass and tire

被引：100
作者：
Cao, Qing [1 ,2 ,3 ]
Jin, Li'e [1 ,2 ,3 ]
Bao, Weiren [2 ,3 ]
Lv, Yongkang [2 ,3 ]
机构：
[1] Taiyuan Univ Technol, Inst Chem Engn & Technol, Taiyuan 030024, Peoples R China
[2] Taiyuan Univ Technol, Key Lab Coal Sci & Technol Shanxi Prov, Taiyuan 030024, Peoples R China
[3] Taiyuan Univ Technol, Minist Educ, Taiyuan 030024, Peoples R China
来源：
FUEL PROCESSING TECHNOLOGY | 2009年 / 90卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Co-pyrolysis; Biomass; Waste tire; Oil; Disposal; WOOD BIOMASS; CATALYTIC CRACKING; PART; LIQUIDS; HYDROGEN; MODEL; MIXTURES; ENGINES; ACID;
D O I：
10.1016/j.fuproc.2008.10.005
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Co-pyrolysis of wood biomass and waste tire with such catalysts as SBA-15, MCM-41 and HZSM-5 was carried out in a fixed-bed reactor. The influences of the mixture composition on liquid yield and characteristics of the oil were investigated. The properties of the oil were determined by gel permeation chromatograph (GPC), elemental analyzer (EA), thermal analyzer (TA), densimeter, ubbelohde viscosimeter and compared with that of diesel oil 0#. The contents of the polycyclic aromatic hydrocarbons (PAHs) in the oils were also determined by gas chromatograph (GC). The result shows that co-pyrolysis is in favor of inhibiting the formation of polycyclic aromatic hydrocarbons (PAHs) produced from tire. There exist a hydrogen transfer and a synthetic effect during co-pyrolysis of the biomass and tire. They improve the quality of the oil. SBA-15 as a catalyst is more significant than MCM-41 or HZSM-5 for reducing the density and viscosity of the oil and it can effectively decompose some large molecular compounds into small ones. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：337 / 342
页数：6
相关论文
共 27 条
[1]   Pyrolysis of biomass in the presence of Al-MCM-41 type catalysts [J].
Adam, J ;
Blazsó, M ;
Mészarós, E ;
Stöcker, M ;
Nilsen, MH ;
Bouzga, A ;
Hustad, JE ;
Gronli, M ;
Oye, G .
FUEL, 2005, 84 (12-13) :1494-1502
[2]   Hydrogen production by catalytic steam reforming of acetic acid, a model compound of biomass pyrolysis liquids [J].
Bimbela, F. ;
Oliva, M. ;
Ruiz, J. ;
Garcia, L. ;
Arauzo, J. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2007, 79 (1-2) :112-120
[3]   Principles and practice of biomass fast pyrolysis processes for liquids [J].
Bridgwater, AV .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1999, 51 (1-2) :3-22
[4]  
[曹青 CAO Qing], 2007, [化工学报, Journal of Chemical Industry and Engineering (China)], V58, P1283
[5]   Development of emulsions from biomass pyrolysis liquid and diesel and their use in engines - Part 1: emulsion production [J].
Chiaramonti, D ;
Bonini, A ;
Fratini, E ;
Tondi, G ;
Gartner, K ;
Bridgwater, AV ;
Grimm, HP ;
Soldaini, I ;
Webster, A ;
Baglioni, P .
BIOMASS & BIOENERGY, 2003, 25 (01) :85-99
[6]   Overview of applications of biomass fast pyrolysis oil [J].
Czernik, S ;
Bridgwater, AV .
ENERGY & FUELS, 2004, 18 (02) :590-598
[7]   Human mesenchymal stem cells favour healing of the cutaneous radiation syndrome in a xenogenic transplant model [J].
Francois, Sabine ;
Mouiseddine, Moubarak ;
Mathieu, Noelle ;
Semont, Alexandra ;
Monti, Pascale ;
Dudoignon, Nicolas ;
Sache, Amandine ;
Boutarfa, Asma ;
Thierry, Dominique ;
Gourmelon, Patrick ;
Chapel, Alain .
ANNALS OF HEMATOLOGY, 2007, 86 (01) :1-8
[8]   Catalytic steam reforming of bio-oils for the production of hydrogen: effects of catalyst composition [J].
Garcia, L ;
French, R ;
Czernik, S ;
Chornet, E .
APPLIED CATALYSIS A-GENERAL, 2000, 201 (02) :225-239
[9]   A model for the evaporation of biomass pyrolysis oil droplets [J].
Hallett, WLH ;
Clark, NA .
FUEL, 2006, 85 (04) :532-544
[10]   Biomass to fuels -: Upgrading of flash pyrolysis oil by reactive distillation using a high boiling alcohol and acid catalysts [J].
Mahfud, F. H. ;
Melian-Cabrera, I. ;
Manurung, R. ;
Heeres, H. J. .
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, 2007, 85 (B5) :466-472
123