Syntheses, Structures, and Characterization of Two Novel Copper(II) and Cadmium(II) Compounds Based on Pyridyl Conjugated 1,2,3-Triazole

被引：3

作者：

Hong, Jin-Long ^{[1
]}

Qu, Zhi-Rong ^{[2
]}

Ma, Hua-Jun ^{[2
]}

Wang, Gai-Gai ^{[1
]}

Zhao, Hong ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China

[2] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 311121, Zhejiang, Peoples R China

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2014年 / 35卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Triazole; Copper(II) complex; Cadmium(II) complex; Crystal structure; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; RETICULAR SYNTHESIS; CHEMISTRY; LIGAND; COMPLEXES; SERIES; FUNCTIONALITY; DESIGN; SYSTEM;

D O I：

10.5012/bkcs.2014.35.5.1495

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new complexes with 5-methyl-1-(pyridine-3-yl)-1H-1,2,3-triazole-4-carboxylic acid (Hmptc) ligand: [Cd(mptc)(2)(H2O)(4)] (1) and [Cu(mptc)(4)center dot 2H(2)O](n) (2) were prepared and their crystal structures were determined by single crystal X-ray diffraction analyses. In complex 1, the Cd(II) ions coordinates with the pyridyl nitogen atom from the Hmptc ligand, forming a mononuclear Cd(II) compound. Complex 2 exhibits a novel two-dimensional (2D) polymer in which four Hmptc ligands stabilize the Cu(II) atom. And the coordination involves one nitrogen atom of the triazole, one oxygen atom of the carboxylic acid and the pyridyl nitrogen atom. In addition, FT-IR and solid-state fluorescent emission spectroscopy of two compounds have been determined.

引用

页码：1495 / 1500

页数：6

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