Alignment of the endohedral fullerenes N@C60 and N@C70 in a liquid-crystal matrix -: art. no. 061201

被引:35
作者
Meyer, C
Harneit, W
Lips, K
Weidinger, A
Jakes, P
Dinse, KP
机构
[1] Hahn Meitner Inst Berlin GmbH, D-14109 Berlin, Germany
[2] Tech Univ Darmstadt, D-64287 Darmstadt, Germany
来源
PHYSICAL REVIEW A | 2002年 / 65卷 / 06期
关键词
D O I
10.1103/PhysRevA.65.061201
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Endohedral fullerenes N@C-60 and N@C-70 were dissolved in a liquid crystal and investigated by electron paramagnetic resonance. Sharp, liquid solution like spectra are observed. However, contrary to the usual solution spectra, the lines are split, indicating that the electron shell of the enclosed nitrogen atom is deformed and that an alignment with respect to the magnetic-field axis is achieved. The present results are of practical interest for controlling the interaction of endohedral fullerenes in a quantum computer.
引用
收藏
页码:612011 / 612014
页数:4
相关论文
共 50 条
[41]   Ferroelectric smectic-C* liquid-crystal phase:: Reexamination of the electric-field influence -: art. no. 061704 [J].
Kutnjak, Z .
PHYSICAL REVIEW E, 2004, 70 (06)
[42]   Electron delocalization and dimerization in solid C59N doped C60 fullerene -: art. no. 066603 [J].
Rockenbauer, A ;
Csányi, G ;
Fülöp, F ;
Garaj, S ;
Korecz, L ;
Lukács, R ;
Simon, F ;
Forró, L ;
Pekker, S ;
Jánossy, A .
PHYSICAL REVIEW LETTERS, 2005, 94 (06)
[43]   Polaron in a one-dimensional C60 crystal -: art. no. 155410 [J].
Belosludov, VR ;
Inerbaev, TM ;
Belosludov, RV ;
Kawazoe, Y .
PHYSICAL REVIEW B, 2003, 67 (15)
[44]   High-precision measurement of the electron spin g factor of trapped atomic nitrogen in the endohedral fullerene N@C60 [J].
Wittmann, J. J. ;
Can, T. V. ;
Eckardt, M. ;
Harneit, W. ;
Griffin, R. G. ;
Corzilius, B. .
JOURNAL OF MAGNETIC RESONANCE, 2018, 290 :12-17
[45]   Repulsive solvent-induced interaction between C60 fullerenes in water -: art. no. 011502 [J].
Li, LW ;
Bedrov, D ;
Smith, GD .
PHYSICAL REVIEW E, 2005, 71 (01)
[46]   Aggregation and interactions of C60 and C70 fullerenes in neat N-methylpyrrolidinone and in N-methylpyrrolidinone/toluene mixtures [J].
Alfè, M ;
Apicella, B ;
Barbella, R ;
Bruno, A ;
Ciajolo, A .
CHEMICAL PHYSICS LETTERS, 2005, 405 (1-3) :193-197
[47]   Synthesis of large macrocyclic azacalix[n]pyridines (n=6-9) and their complexation with fullerenes C60 and C70 [J].
Zhang, En-Xuan ;
Wang, De-Xian ;
Zheng, Qi-Yu ;
Wang, Mei-Xiang .
ORGANIC LETTERS, 2008, 10 (12) :2565-2568
[48]   Inner-shell near-threshold photoionization of A@C60 endohedral atoms -: art. no. 023201 [J].
Baltenkov, AS ;
Dolmatov, VK ;
Manson, ST .
PHYSICAL REVIEW A, 2002, 66 (02) :1-9
[49]   Synthesis and Properties of Endohedral Aza[60]fullerenes: H2O@C59N and H2@C59N as Their Dimers and Monomers [J].
Hashikawa, Yoshifumi ;
Murata, Michihisa ;
Wakamiya, Atsushi ;
Murata, Yasujiro .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (12) :4096-4104
[50]   Clustering dynamics of fullerenes in C-60/C-70-chemically modified poly(N-vinylcarbazole) [J].
Zhao, L ;
Zhang, J ;
Zhang, RJ ;
Li, YF ;
Chen, YF ;
Cai, RF ;
Huang, Z .
CHEMICAL PHYSICS LETTERS, 1996, 263 (1-2) :235-240