Perturbation theory for confined systems

被引：3

作者：

Fernandez, Francisco M. ^{[1
]}

机构：

[1] UNLP, CCT La Plata CONICET, INIFTA, Div Quim Teor, RA-1900 La Plata, Buenos Aires, Argentina

来源：

JOURNAL OF MATHEMATICAL CHEMISTRY | 2014年 / 52卷 / 01期

关键词：

Confined systems; Perturbation theory; Helium atom; ATOM;

D O I：

10.1007/s10910-013-0252-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We discuss the application of perturbation theory to a system of particles confined in a spherical box. A simple argument shows that the particles behave almost independently in sufficiently strong confinement. We choose the helium atom with a moving nucleus as a particular example and compare results of first order with those for the nucleus clamped at the center of the box. We provide a suitable explanation for some numerical results obtained recently by other authors.

引用

页码：174 / 177

页数：4

共 6 条

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