A dynamic equilibrium method for the SnO2-based ozone sensors using UV-LED continuous irradiation

被引:32
作者
Jeng, Chien-Chung [1 ,2 ]
Chong, Paul J. H. [1 ]
Chiu, Cheng-Chung [2 ]
Jiang, Guo-Jhen [1 ]
Lin, Hung-Ju [2 ]
Wu, Ren-Jang [3 ]
Wu, Chiu-Hsien [1 ,2 ]
机构
[1] Natl Chung Hsing Univ, Inst Nanosci, Taichung 402, Taiwan
[2] Natl Chung Hsing Univ, Dept Phys, Taichung 402, Taiwan
[3] Providence Univ, Dept Appl Chem, Taichung 43301, Taiwan
关键词
Dynamics equilibrium; Gas sensor; Ozone; Time constant; UV-LED; Room temperature sensing; GAS SENSOR; FILMS; ACTIVATION;
D O I
10.1016/j.snb.2014.01.034
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
We report the sensing characteristics of SnO2 thin-film gas sensors operated under room temperature. The sensor was continuously irradiated during sensing with ultraviolet (UV) light from a single 370-nm UV light-emitting diode (LED). The saturation resistance and sensitivity of the developed SnO2 sensor were observed to depend on the LED power. The SnO2 films produced a good response to ozone (O-3), and this response showed good reproducibility under a dynamic O-3 concentration of 5-14 ppm, and under a stable concentration. The time constant of absorption as a function of the trace O-3 concentration was analyzed, and the results showed a promising correlation between time constant and concentration. The humidity affects the lowest measured resistance, but not the response. We propose the presence of a dynamic equilibrium between the background conditions to explain the working mechanism of our sensor system. Crown Copyright (C) 2014 Published by Elsevier BY. All rights reserved.
引用
收藏
页码:702 / 706
页数:5
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