Synthesis and crystal structure of a new one-dimensional system with end-to-end single dicyanamide bridges between nickel(II) centres

被引:20
作者
Li, BL [1 ]
Ding, JG
Lang, JP
Xu, Z
Chen, JT
机构
[1] Suzhou Univ, Dept Chem & Chem Engn, Suzhou 215006, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
关键词
crystal structure; dicyanamide; hydrogen bonding; nickel complex; magnetic properties;
D O I
10.1016/S0022-2860(02)00327-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The complex [Ni(tn)(2)[N(CN)(2)}]ClO4 (m = trimethylenediamine) has been synthesized and the structure has been determined. The complex forms a one-dimensional chain structure via the bidentate bridging ligand dicyanamide. A two-dimensional networks is formed via interchain hydrogen bond interactions. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:175 / 179
页数:5
相关论文
共 16 条
[1]  
ALBADA GAV, 2000, INORG CHIM ACTA, V298, P221
[2]  
[Anonymous], 2015, Acta Crystallogr., V71, P3
[3]   Structure and molecular magnetism of the rutile-related compounds M(dca)2, M = CoII, NiII, CuII, dca = dicyanamide, N(CN)2- [J].
Batten, SR ;
Jensen, P ;
Moubaraki, B ;
Murray, KS ;
Robson, R .
CHEMICAL COMMUNICATIONS, 1998, (03) :439-440
[4]   Two new one-dimensional systems with end-to-end single dicyanamide bridges between manganese(II) centres: structural and magnetic properties [J].
Claramunt, A ;
Escuer, A ;
Mautner, FA ;
Sanz, N ;
Vicente, R .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (15) :2627-2630
[5]  
Jensen P, 2000, CHEM-EUR J, V6, P3186, DOI 10.1002/1521-3765(20000901)6:17<3186::AID-CHEM3186>3.3.CO
[6]  
2-M
[7]   trans-Bis(dicyanamido-N)tetrakis(4-methylimidazole-N-1)nickel(II) [J].
Kozisek, J ;
Paulus, H ;
Dankova, M ;
Hvastijova, M .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :3019-3020
[8]   Hard magnets based on transition metal complexes with the dicyanamide anion, {N(CN)2}- [J].
Kurmoo, M ;
Kepert, CJ .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (12) :1515-1524
[9]  
Manson JL, 1999, J SOLID STATE CHEM, V145, P369, DOI 10.1006/jssc.1999.8059
[10]   Spontaneous magnetization in the M[N(CN)2]2 (M = Cr, Mn) weak ferromagnets [J].
Manson, JL ;
Kmety, CR ;
Epstein, AJ ;
Miller, JS .
INORGANIC CHEMISTRY, 1999, 38 (11) :2552-+