Hydrothermal synthesis, crystal structure and luminescence property of a three dimensional Sm(III) coordination polymer with 2,5-pyridinedicarboxylic acid

被引：12

作者：

Gangu, Kranthi Kumar ^{[1
]}

Dadhich, Anima S. ^{[1
]}

Mukkamala, Saratchandra Babu ^{[1
]}

机构：

[1] GITAM Univ, Dept Chem, Visakhapatnam 530045, Andhra Pradesh, India

来源：

JOURNAL OF CHEMICAL SCIENCES | 2015年 / 127卷 / 12期

关键词：

Hydrothermal synthesis; coordination polymer; X-ray diffraction; samarium (III); luminescence property; LIGANDS; FRAMEWORKS; COMPLEXES; PHOTOLUMINESCENCE; SERIES;

D O I：

10.1007/s12039-015-0985-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel three dimensional coordination polymer [Sm(2,5-pydc)(NO3)(H2O)] a <...(H2O) (2,5-pydc = 2,5-pyridine dicarboxylate) (1) had been synthesized hydrothermally and characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction analysis. This coordination polymer crystallized in the monoclinic space group P2/n with cell parameters a= 9.3610(4) , b= 8.3498(3) , c= 16.7159(8) , beta= 106.31(0)(a similar to), V= 1253.98(184) (3). Thermogravimetric analysis revealed that complex 1 is stable up to 400(a similar to)C which on photoexcitation at 365 nm exhibited yellow emission at 583 nm.

引用

页码：2225 / 2230

页数：6

共 28 条

[1] Using long bis(4-pyridyl) ligands designed for the self-assembly of coordination frameworks and architectures
Banfi, S
Carlucci, L
Caruso, E
Ciani, G
Proserpio, DM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (13): : 2714 - 2721
[2] Synthesis, crystal structure and photo luminescent property of a 3D metal-organic hybrid of Cd(II) constructed by two different bridging carboxylate
Bhattacharya, Biswajit
Dey, Rajdip
Ghoshal, Debajyoti
[J]. JOURNAL OF CHEMICAL SCIENCES, 2013, 125 (03) : 661 - 666
[3] Burak A, 2015, POLYHEDRON, V88, P176
[4] Syntheses and characterization of the samarium(III)-copper(II) 3D coordination network constructed by iminodiacetic acid
Cai, YP
Li, GB
Zhan, QG
Sun, F
Zhang, JG
Gao, S
Xu, AW
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (12) : 3729 - 3734
[5] New examples of d10 metal-organic frameworks based on 4,4′-(hexafluoroisopropylidene)diphthalic acid: Synthesis, crystal structure and luminescence
Chen, Xiaoli
Zhang, Xiaoge
Gao, Loujun
Ma, Hongyan
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2015, 1085 : 45 - 51
[6] Utility and synthetic uses of Mannich reaction: An efficient route for synthesis of thiadiazino-[1,3,5][3,2-a]benzimidazoles
El-Wareth, A
Sarhan, AO
Abdel-Hafez, SH
El-Sherief, H
Aboel-Fadl, T
[J]. SYNTHETIC COMMUNICATIONS, 2006, 36 (08) : 987 - 996
[7] Silver(I) coordination polymer and nine-coordinated cadmium(II) complex with dimethyl pyridine-2,6-dicarboxylate supported by solid state and electrochemical studies
Hakimi, Mohammad
Moeini, Keyvan
Mardani, Zahra
Schuh, Esther
Mohr, Fabian
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (07) : 1129 - 1141
[8] Hydrothermal synthesis, crystal structure and photoluminescent properties of a novel 3-D coordination polymer [Cd2(pydc)2(H2O)]n (pydc = pyridine-2,3-dicarboxylate)
Han, Zheng-Bo
Ma, Yi
Sun, Zhen-Gang
You, Wan-Sheng
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (08) : 844 - 847
[9] N-donor ligand mediated assembly of divalent zinc and cadmium coordination polymers based on 2,3,2′,3′-thiaphthalic acid: structures and properties
Li, Jia-Bin
Dong, Xi-Yan
Cao, Li-Hui
Zang, Shuang-Quan
Mak, Thomas C. W.
[J]. CRYSTENGCOMM, 2012, 14 (13): : 4444 - 4453
[10] Syntheses of Metal-2-(Pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate Networks with Topological Diversity: Gas Adsorption, Thermal Stability and Fluorescent Emission Properties
Li, Xia
Wu, Ben-Lai
Niu, Cao-Yuan
Niu, Yun-Yin
Zhang, Hong-Yun
[J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (08) : 3423 - 3431

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