Synthesis of novel 1,2,3-triazole based silatranes via "click silylation"

被引：23
|
作者：
Singh, Gurjaspreet [1 ]
Mangat, Satinderpal Singh
Singh, Jandeep
Arora, Aanchal
Garg, Mridula
机构：
[1] Panjab Univ, Dept Chem, Chandigarh 160014, India
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 769卷
关键词：
Silatrane; Click silylation; Triethoxysilane; 1,2,3-Triazole; Trisalkoxyamine; SURFACE MODIFICATION; SILICON; STEREOCHEMISTRY; PENTACOORDINATE; REACTIVITY; CHEMISTRY; AZIDE;
D O I：
10.1016/j.jorganchem.2014.07.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A single step reaction for the synthesis of novel 1,2,3-triazole based silatranes (TBS)-scaffolds (2a-2o) using polyfunctionalised organotriethoxysilanes (1a-1l) as precursors is described. The synthesized silatranes are the first compounds of this type and hydrolytically more stable than their open chain analogues. The structures of 2a-2o were characterized by IR, NMR (H-1 and C-13) and mass spectroscopy studies. (c) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：124 / 129
页数：6
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