Dinuclear oxidative addition reactions using an isostructural series of Ni2, Co2, and Fe2 complexes

被引：23

作者：

Behlen, Michael J. ^{[1
]}

Zhou, You-Yun ^{[1
]}

Steiman, Talia J. ^{[1
]}

Pal, Sudpta ^{[1
]}

Hartline, Douglas R. ^{[1
]}

Zeller, Matthias ^{[1
]}

Uyeda, Christopher ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, 560 Oval Dr, W Lafayette, IN 47905 USA

来源：

DALTON TRANSACTIONS | 2017年 / 46卷 / 17期

基金：

美国国家科学基金会;

关键词：

EXHIBITING SPIN-CROSSOVER; REDOX-ACTIVE LIGANDS; NICKEL-COMPLEXES; BOND; ACTIVATION; CATALYSIS; MONONUCLEAR; REACTIVITY; CHEMISTRY; MODELS;

D O I：

10.1039/c6dt04465d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A family of low-valent Ni-2, Co-2, and Fe-2 naphthyridine-diimine (NDI) complexes is presented. Ligand-based pi* orbitals are sufficiently low-lying to fall within the metal 3d manifold, resulting in electronic structures that are highly delocalized across the conjugated [NDI]M-2 system. This feature confers stability to metalmetal interactions during two-electron redox reactions, as demonstrated in a prototypical oxidative addition of allyl chloride.

引用

页码：5493 / 5497

页数：5

共 36 条

[1] Dinuclear Pd(I) complexes-solely precatalysts? Demonstration of direct reactivity of a Pd(I) dimer with an aryl iodide [J].

Bonney, Karl J. ;

Proutiere, Fabien ;

Schoenebeck, Franziska .

CHEMICAL SCIENCE, 2013, 4 (12) :4434-4439

[2] Iron-catalyzed [2π+2π] cycloaddition of α,ω-dienes:: The importance of redox-active supporting ligands [J].

Bouwkamp, Marco W. ;

Bowman, Amanda C. ;

Lobkovsky, Emil ;

Chirik, Paul J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (41) :13340-13341

[3] Synthesis and Electronic Structure Determination of N-Alkyl-Substituted Bis(imino)pyridine Iron Imides Exhibiting Spin Crossover Behavior [J].

Bowman, Amanda C. ;

Milsmann, Carsten ;

Bill, Eckhard ;

Turner, Zoe R. ;

Lobkovsky, Emil ;

DeBeer, Serena ;

Wieghardt, Karl ;

Chirik, Paul J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (43) :17353-17369

[4]

Cammarota R. C., 2016, COORD CHEM IN PRESS

[5] Unusual Thiolate-Bridged Diiron Clusters Bearing the cis-HN=NH Ligand and Their Reactivities with Terminal Alkynes [J].

Chen, Yanhui ;

Liu, Litao ;

Peng, Ying ;

Chen, Pingping ;

Luo, Yi ;

Qu, Jingping .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1147-1149

[6] Radical Ligands Confer Nobility on Base-Metal Catalysts [J].

Chirik, Paul J. ;

Wieghardt, Karl .

SCIENCE, 2010, 327 (5967) :794-795

[7] REACTIONS OF METAL-METAL MULTIPLE BONDS .7. ADDITION OF THE HALOGENS CL2, BR2, AND I2 AND DIISOPROPYL PEROXIDE TO HEXAISOPROPOXYDIMOLYBDENUM (M=M) - DINUCLEAR OXIDATIVE-ADDITION REACTIONS ACCOMPANIED BY METAL-METAL BOND-ORDER CHANGES FROM 3 TO 2 TO 1 [J].

CHISHOLM, MH ;

KIRKPATRICK, CC ;

HUFFMAN, JC .

INORGANIC CHEMISTRY, 1981, 20 (03) :871-876

[8] Catalytic Applications of Early/Late Heterobimetallic Complexes [J].

Cooper, Benjamin G. ;

Napoline, J. Wesley ;

Thomas, Christine M. .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2012, 54 (01) :1-40

[9] Synthesis and Properties of NHC-Supported Palladium(I) Dimers with Bridging Allyl, Cyclopentadienyl, and Indenyl Ligands [J].

Dai, Wei ;

Chalkley, Matthew J. ;

Brudvig, Gary W. ;

Hazari, Nilay ;

Melvin, Patrick R. ;

Pokhrel, Ravi ;

Takase, Michael K. .

ORGANOMETALLICS, 2013, 32 (18) :5114-5127

[10] Oxidative Addition of Carbon-Carbon Bonds with a Redox-Active Bis(imino)pyridine Iron Complex [J].

Darmon, Jonathan M. ;

Stieber, S. Chantal E. ;

Sylvester, Kevin T. ;

Fernandez, Ignacio ;

Lobkovsky, Emil ;

Semproni, Scott P. ;

Bill, Eckhard ;

Wieghardt, Karl ;

DeBeer, Serena ;

Chirik, Paul J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (41) :17125-17137

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