Study of the compensation mechanism of La2O3-doped BaTiO3

被引:3
作者
Ramajo, M [1 ]
Brzozowski, E [1 ]
Castro, MS [1 ]
机构
[1] Univ Nacl Mar del Plata, CONICET, INTEMA, Inst Invest Ciencia & Tecnol Mat, RA-7608 Mar Del Plata, Buenos Aires, Argentina
来源
BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO | 2004年 / 43卷 / 03期
关键词
BaTiO3; electrical properties; ionic defects; dopants; microstructure;
D O I
10.3989/cyv.2004.v43.i3.477
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this work, the incorporation of several concentrations of the La3+ ion into the BaTiO3 lattice was studied. It was verified that low La3+ concentrations inhibits the grain growth and produces a highly densified material. However, a delay in the sintering behavior in ceramics with high doping concentrations was observed. The La3+ donor incorporation in the BaTiO3 modified the defects structure, favored titanium vacancies formation, and stabilized a pseudocubic phase. This effect influences the dielectric properties and the cubic-tetragonal transition temperature.
引用
收藏
页码:691 / 694
页数:4
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