Kinetics of oxidation of hexacyanoferrate(II) by N-bromosuccinimide in aqueous alkaline medium

被引：0
|
作者：
Kamble, DL [1 ]
Nandibewoor, ST [1 ]
机构：
[1] KARNATAK UNIV,DEPT CHEM,DHARWAD 580003,KARNATAKA,INDIA
来源：
POLISH JOURNAL OF CHEMISTRY | 1997年 / 71卷 / 01期
关键词：
oxidation; hexacyanoferrate(N); N-bromosuccinimide; kinetics;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction between hexacyanoferrate(II) and N-bromosuccinimide in aqueous alkaline medium is of both first order in [hexacyanoferrate(II)] and [N-bromosuccinimide], whereas inverse fractional order in [alkali]. The active species of hexacyanoferrate(II) and NBS are Fe(CN)(6)(4-) and HOBr, respectively. A mechanism based on the experimental results is proposed and the constants involved in the mechanism are evaluated.
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页码：91 / 95
页数：5
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