Functionalization of [60]Fullerene via Palladium-Catalyzed C-H Bond Activation

被引：40
作者：
Wang, Guan-Wu [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, iChEM Collaborat Innovat Ctr Chem Energy Mat, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
来源：
C-H BOND ACTIVATION AND CATALYTIC FUNCTIONALIZATION I | 2016年 / 55卷
关键词：
60]Fullerene; Annulation; Carbocycle; C-H activation; Heterocycle; Palladium catalyst; DECARBOXYLATIVE ORTHO-ACYLATION; PD(II)-CATALYZED AMINATION; ANILIDES; HETEROANNULATION; TETRAALLYLATION; CONSTRUCTION; SULFONAMIDES; ALKOXYLATION; DERIVATIVES; FULLERENE;
D O I：
10.1007/3418_2015_128
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The palladium-catalyzed C-H bond activation strategy has been successfully applied to fullerene chemistry, and several types of [60] fullerene-fused heterocycles and carbocycles have been obtained. The synthesis of [60] fullerene-fused indolines, isoquinolinones, azepines, tetrahydroisoquinolines, tetrahydrobenzazepines, sultones, tetrahydrobenzooxepines/isochromans, and dihydrophenanthrenes has been achieved by the palladium-catalyzed reactions of [60] fullerene with anilides, benzamides, N-sulfonyl-2-aminobiaryls, N-benzyl sulfonamides, N-(2-arylethyl) sulfonamides, arylsulfonic acids, 2-phenylethyl/benzyl alcohols, and 2-arylbenzoic acids, respectively.
引用
收藏
页码：119 / 136
页数：18
相关论文
共 50 条
  • [31] Palladium-Catalyzed intramolecular C-H Activation/C-C Bond Formation: A Straightforward Synthesis of Phenanthridines
    Peng, Jinsong
    Chen, Tonghui
    Chen, Chunxia
    Li, Bin
    JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (22) : 9507 - 9513
  • [32] Synthesis of xanthones through the palladium-catalyzed carbonylation/C-H activation sequence
    Xu, Yingmeng
    Zhou, Jing
    Zhang, Congcong
    Chen, Ke
    Zhang, Tao
    Du, Zhenting
    TETRAHEDRON LETTERS, 2014, 55 (47) : 6432 - 6434
  • [33] Palladium-catalyzed carbonylative C-H activation of arenes with norbornene as the coupling partner
    Chen, Jianbin
    Natte, Kishore
    Wu, Xiao-Feng
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 803 : 9 - 12
  • [34] Direct C-3-Alkenylation of Quinolones via Palladium-Catalyzed C-H Functionalization
    Li, Mingzong
    Li, Liangxi
    Ge, Haibo
    ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (14-15) : 2445 - 2449
  • [35] Palladium-Catalyzed Carbonylative C-H Activation of Heteroarenes
    Wu, Xiao-Feng
    Anbarasan, Pazhamalai
    Neumann, Helfried
    Beller, Matthias
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (40) : 7316 - 7319
  • [36] Palladium-Catalyzed Oxidative Double C-H Functionalization/Carbonylation for the Synthesis of Xanthones
    Zhang, Hua
    Shi, Renyi
    Gan, Pei
    Liu, Chao
    Ding, Anxing
    Wang, Qiuyi
    Lei, Aiwen
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (21) : 5204 - 5207
  • [37] A Direct Palladium-Catalyzed Route for the Synthesis of Benzo[a]carbazoles through Sequential C-C Bond Formation and C-H Bond Functionalization
    Kianmehr, Ebrahim
    Ghanbari, Mohammad
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 2012 (02) : 256 - 259
  • [38] Palladium-catalyzed C-N bond formation via direct C-H bond functionalization. Recent developments in heterocyclic synthesis
    Beccalli, Egle M.
    Broggini, Gianluigi
    Fasana, Andrea
    Rigamonti, Micol
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (01) : 277 - 295
  • [39] Palladium-Catalyzed Transient Chirality Transfer and Atroposelective C-H Functionalization to Access Quaternary Stereocenters
    Han, Lu-Lu
    Cui, Yu-Ming
    Yang, Qin
    Fang, Li-Lei
    Xu, Li-Wen
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (46)
  • [40] Palladium-Catalyzed Synthesis of Triphenylenes via Sequential C-H Activation and Decarboxylation
    Yang, Yuzhong
    Zhou, Bang
    Zhu, Xiaoming
    Deng, Guobo
    Liang, Yun
    Yang, Yuan
    ORGANIC LETTERS, 2018, 20 (17) : 5402 - 5405
12345