Synthesis and Crystal Structures of Two Zinc(II) Complexes with the Schiff Bases 2-[(3-Diethylaminopropylimino)methyl]phenol and 1-[(3-Diethylaminopropylimino)methyl]naphthalen-2-ol

被引：1

作者：

Lin, Hong-Wei ^{[1
]}

机构：

[1] Huaihua Univ, Dept Chem, Huaihua 418008, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2009年 / 39卷 / 02期

关键词：

synthesis; crystal structure; Schiff base; zinc(II) complex; NICKEL(II);

D O I：

10.1080/15533170902762595

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new structurally similar mononuclear Schiff base zinc(II) complexes, [ZnBr2L1] (1) and [ZnI2L2] (2) (L1 = 2-[(3-diethylaminopropylimino)methyl]phenol, L2 = 1-[(3-diethylaminopropylimino)methyl]naphthalen-2-ol), have been synthesized and characterized by elemental analysis, IR, and single crystal X-ray diffraction. The Zn atom in each of the complexes is four-coordinated by one phenolate oxygen atom and one imine nitrogen atom of a Schiff base ligand and by two halide ligands, forming a tetrahedral geometry. In the crystal structures of both complexes, molecules are linked through intermolecular hydrogen bonds of types N-H O, forming chains running along the b axis. The similar Schiff bases used in the preparation of the complexes with zinc(II) halides can result in the similar structures of the final products.

引用

页码：73 / 77

页数：5

共 50 条

[31] DNA binding and cleavage, cytotoxicity and antimicrobial studies of Co(II), Ni(II), Cu(II) and Zn(II) complexes of 1-((E)-(4-(trifluoromethoxy)phenylimino)methyl)naphthalen-2-ol Schiff base [J].

Rambabu, Aveli ;

Kumar, Marri Pradeep ;

Ganji, Nirmala ;

Daravath, Sreenu ;

Shivaraj .

JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS, 2020, 38 (01) :307-316

[32] Synthesis, Characterization and Antimicrobial Evaluation of Novel 1-[(1-Phenyl-1h-Tetrazol-5-yl-imino)-Methyl]-Naphthalen-2-ol and Its Cu(II), Co(II) Complexes [J].

Mariyam ;

Oktapianti, Siska .

ORIENTAL JOURNAL OF CHEMISTRY, 2018, 34 (03) :1541-1550

[33] Crystal structures and antimicrobial activity of zinc(II) and nickel(II) complexes of 5-bromo-(((2-(phenylamino)ethyl)imino)methyl)phenol [J].

Wu, Jiahui ;

Zhang, Xiaoqing ;

Zhang, Jiahui ;

Mao, Yongxin ;

Lan, Xue ;

Miao, Linan ;

Aishanjiang, Buheliqigu ;

Shi, Dahua ;

You, Zhonglu .

JOURNAL OF COORDINATION CHEMISTRY, 2023, 76 (9-10) :1214-1230

[34] Synthesis and Crystal Structures of Two Dinuclear Nickel(II) Complexes Derived from 2-Ethoxy-6-[(2-phenylaminoethylimino)methyl]phenol [J].

Hong, Zhe .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (09) :601-605

[35] Synthesis, crystal structures, quantum chemical studies and corrosion inhibition potentials of 4-(((4-ethylphenyl)imino)methyl)phenol and (E)-4-((naphthalen-2-ylimino) methyl) phenol Schiff bases [J].

Elemike, Elias E. ;

Nwankwo, Henry U. ;

Onwudiwe, Damian C. ;

Hosten, Eric C. .

JOURNAL OF MOLECULAR STRUCTURE, 2017, 1147 :252-265

[36] SYNTHESIS, CRYSTAL STRUCTURES AND PRELIMINARY ANTIBACTERIAL ACTIVITIES OF NICKEL(II) AND ZINC(II) COMPLEXES DERIVED FROM 2-BROMO-6-[(3-CYCLOHEXYLAMINOPROPYLIMINO) METHYL]PHENOL [J].

Li, Wei ;

Ding, Yi ;

Cheng, Xiao-Shan ;

You, Zhonglu .

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2015, 60 (03) :3034-3037

[37] A series of zinc(II) and copper(II) complexes derived from 5-bromo-2((2-(dimethylamino)ethylimino)methyl)phenol: syntheses, characterization, crystal structures and antimicrobial activity [J].

Sang, Ya-Li ;

Zou, Li-Fei ;

Jin, Rui-Fa ;

Liu, Yan-Hua ;

Lin, Xue-Song ;

Zhang, Xin-Hao .

JOURNAL OF COORDINATION CHEMISTRY, 2021, 74 (12) :1929-1946

[38] Synthesis, Crystal Structures, and Antibacterial Activity of Copper(II) and Cobalt(III) Complexes Derived from 2-{1-[2-(2-Hydroxyethylamino)ethylimino]ethyl}phenol [J].

Hang, Zhi-Xi ;

Dong, Bo ;

Wang, Xing-Wen .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2011, 41 (02) :193-198

[39] Syntheses and Crystal Structures of Two Acetato-Bridged Trinuclear Zinc(II) Complexes Derived from 4-Chloro-2-[(2-ethylaminoethylimino)methyl]phenol and 4-Chloro-2-[(2-isopropylaminoethylimino)methyl]phenol [J].

Hui, Rui-Hua ;

Zhou, Peng ;

You, Zhong-Lu .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2009, 39 (04) :211-215

[40] Syntheses and Crystal Structures of Two Copper(II) and Nickel(II) Complexes with 2-Ethoxy-6-[(2-isopropyl-aminoethylimino)methyl]phenol [J].

Hui, Rui-Hua ;

Zhou, Peng .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2009, 39 (01) :60-64

← 1 2 3 4 5 →