Determination of monomer reactivity ratios in styrene/2-ethylhexylacrylate copolymer

被引：8
作者：
Kavousian, A
Ziaee, F
Nekoomanesh, MH
Leamen, MJ
Penlidis, A [1 ]
机构：
[1] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada
[2] Iran Polymer Inst, Tehran, Iran
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2004年 / 92卷 / 05期
关键词：
styrene; 2-ethylhexylacrylate; copolymerization; modeling; radical polymerization;
D O I：
10.1002/app.20338
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The monomer reactivity ratios for styrene/ 2-ethylhexylacrylate in bulk at 80degreesC were investigated by studying the resulting copolymer composition via H-1-NMR. Composition results were summarized and various methods were employed to estimate the reactivity ratios including the use of the Error-in-Variables-Model (EVM) approach by using the Mayo-Lewis model. The estimates of the reactivity ratios from the EVM method are found to be r(s) = 0.979 and r(EHA) = 0.292. The resulting copolymer has a tendency toward alternation with an azeotrope of f(styrene) = 0.972. (C) 2004 Wiley Periodicals, lnc.
引用
收藏
页码：3368 / 3370
页数：3
相关论文
共 50 条
[31]   Determination of the Monomer Reactivity Ratios in Copolymerization of Two Distinct Dimethacrylates for Dental Use [J].
Sulca, Nicoleta Mihaela ;
Lungu, Adriana ;
Zaharia, Catalin ;
Stan, Raluca ;
Iovu, Horia .
MATERIALE PLASTICE, 2010, 47 (02) :254-258
[32]   Statistical Copolymers of Methyl Methacrylate and 2-Methacryloyloxyethyl Ferrocenecarboxylate: Monomer Reactivity Ratios, Thermal and Electrochemical Properties [J].
Droulia, Margarita ;
Anastasaki, Athina ;
Rokotas, Alexandros ;
Pitsikalis, Marinos ;
Paraskevopoulou, Patrina .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (14) :3080-3089
[33]   Synthesis and spectral and thermal properties of copolymers of (2-cyclopentylidene-1,3-dioxolane-4-yl)methyl methacrylate with styrene and acrylonitrile and the determination of the monomer reactivity ratios [J].
Ilter, Z ;
Soykan, C ;
Koca, M .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (19) :2996-3005
[34]   A reactive copolymer based on Glycidylmethacrylate and Maleic Anhydride: 1-synthesis, characterization and monomer reactivity ratios [J].
Reza Hasanzadeh ;
Peyman Najafi Moghadam ;
Naeimeh Bahri-Laleh ;
Farshid Ziaee .
Journal of Polymer Research, 2016, 23
[35]   Reactivity Ratios for Organotin Copolymer Systems [J].
El-Newehy, Mohamed H. ;
Al-Deyab, Salem S. ;
Al-Hazmi, Ali Mohsen Ali .
MOLECULES, 2010, 15 (04) :2749-2758
[36]   Copolymerization of benzoylphenyl methacrylate with methyl methacrylate: Synthesis, characterization and determination of monomer reactivity ratios [J].
Vijayanand, PS ;
Unnithan, CS ;
Penlidis, A ;
Nanjundan, S .
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2005, A42 (05) :555-569
[37]   Synthesis and characterization of novel acrylic copolymers: Determination of monomer reactivity ratios and biological activity [J].
Patel, MV ;
Dolia, MB ;
Patel, JN ;
Patel, RM .
REACTIVE & FUNCTIONAL POLYMERS, 2005, 65 (03) :195-204
[38]   Synthesis and reactivity ratios of regioisomeric vinyl-1,2,3-triazoles with styrene [J].
Lartey, Michael ;
Gillissen, Martijn ;
Adzima, Brian J. ;
Takizawa, Kenichi ;
Luebke, David R. ;
Nulwala, Hunaid B. .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2013, 51 (16) :3359-3364
[39]   Estimation of Reactivity Ratios in the Copolymerization of Styrene and VeoVa-10 [J].
Santos, Murilo P. ;
Torraga, Maria G. F. ;
Barbosa, Natalia B. ;
Tavares, Denise T. ;
Giudici, Reinaldo .
MACROMOLECULAR REACTION ENGINEERING, 2020, 14 (03)
[40]   Boronated (co)polystyrene: monomer reactivity ratios, thermal behavior and flammability [J].
Wiacek, Malgorzata ;
Wesolek, Dorota ;
Rojewski, Szymon ;
Bujnowicz, Krzysztof ;
Schab-Balcerzak, Ewa .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2015, 26 (01) :49-56
12345