Effect of temperature and high pressure on Mn2+ EPR spectra in K3H(SO4)2 fast-proton conductor

被引：2

作者：

Ostrowski, Adam ^{[1
]}

Krupska, Aldona ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Mol Phys, PL-60179 Poznan, Poland

来源：

PHASE TRANSITIONS | 2006年 / 79卷 / 6-7期

关键词：

proton conductors; phase transitions; electron paramagnetic resonance;

D O I：

10.1080/01411590600892518

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The linewidth Delta H-pp and spin-Hamiltonian parameters under temperature and high hydrostatic pressure by X-band continuous wave electron paramagnetic resonance in the K3H(SO4)(2) crystal were studied. Spin-Hamiltonian parameters, direction cosines and coordination of Mn2+ ion were determined at room temperature. The pressure at 300 MPa leads to the change of hydrogen bond potential and the transition from double well to single well potential moves about 10 K towards a higher temperature.

引用

页码：569 / 575

页数：7

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